The metal aluminium has come into general use with surprising rapidity,
and during the last twenty-five or thirty years the amount of this
metal produced annually has increased from two or three tons to many
thousands of tons. Aluminium occurs naturally in large quantities,
in the form of alumina, or oxide of aluminium, but for a long time
experimenters despaired of ever obtaining the pure metal cheaply
on a commercial scale. The oxides of most metals can be reduced,
that is deprived of their oxygen, by heating them with carbon; but
aluminium oxide holds on to its oxygen with extraordinary tenacity,
and absolutely refuses to be parted from it in this way. One process
after another was tried, without success, and cheap aluminium seemed
to be an impossibility until about 1887, when two chemists, Hall, an
American, and Héroult, a Frenchman, discovered a satisfactory solution
of the problem. These chemists, who were then scarcely out of their
student days, worked quite independently of one another, and it is a
remarkable fact that their methods, which are practically alike, were
discovered at almost the same time. The process is an interesting
mixture of electrolysis and electric heating. An iron crucible
containing a mixture of alumina, fluorspar, and cryolite is heated. The
two last-named substances are quickly fused, and the alumina dissolves
in the resulting fluid. When the mixture has reached the fluid state,
electrodes made of carbon are dipped into it, and a current is passed
through; with the result that oxygen is given off at the anode, and
metallic aluminium is produced at the cathode, in molten drops. This
molten metal is heavier than the rest of the fluid, and so it falls
to the bottom. From here it is drawn off at intervals, while fresh
alumina is added as required, so that the process goes on without
interruption. After the first fusing of the mixture no further outside
heat is required, for the heat produced by the passage of the current
is sufficient to keep the materials in a fluid state. Vast quantities
of aluminium are produced in this way at Niagara Falls, and in Scotland
and Switzerland.
Most of us are familiar with the substance known as caustic soda.
The chemical name for this is sodium hydrate, and its preparation by
electrolysis is interesting. Common salt is a chemical compound of the
metal sodium and the greenish coloured, evil smelling gas chlorine,
its proper name being sodium chloride. A solution of this in water is
placed in a vat or cell, and a current is sent through it. The solution
is then split up into chlorine, at the anode, and sodium at the
cathode. Sodium has a remarkably strong liking for water, and as soon
as it is set free from the chlorine it combines with the water of the
solution, and a new solution of sodium hydrate is formed. The water in
this is then got rid of, and solid caustic soda remains.
Public-domain text, read in full here on John Shaqi.
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