The current from a simple voltaic cell does not remain at a constant
strength, but after a short time it begins to weaken rapidly. The
cell is then said to be polarized, and this polarization is caused by
bubbles of hydrogen gas which accumulate on the surface of the copper
plate during the chemical action. These bubbles of gas weaken the
current partly by resisting its flow, for they are bad conductors,
and still more by trying to set up another current in the opposite
direction. For this reason the simple voltaic cell is unsuitable for
long spells of work, and many cells have been devised to avoid the
polarization trouble. One of the most successful of these is the
Daniell cell. It consists of an outer vessel of copper, which serves
as the copper plate, and an inner porous pot containing a zinc rod.
Dilute sulphuric acid is put into the porous pot and a strong solution
of copper sulphate into the outer jar. When the circuit is closed,
the hydrogen liberated by the action of the zinc on the acid passes
through the porous pot, and splits up the copper sulphate into copper
and sulphuric acid. In this way pure copper, instead of hydrogen, is
deposited on the copper plate, no polarization takes place, and the
current is constant.
Other cells have different combinations of metals, such as silver-zinc,
or platinum-zinc, and carbon is also largely used in place of one
metal, as in the familiar carbon-zinc Leclanché cell, used for ringing
electric bells. This cell consists of an inner porous pot containing
a carbon plate packed round with a mixture of crushed carbon and
manganese dioxide, and an outer glass jar containing a zinc rod and a
solution of sal-ammoniac. Polarization is checked by the oxygen in the
manganese dioxide, which seizes the hydrogen on its way to the carbon
plate, and combines with it. If the cell is used continuously however
this action cannot keep pace with the rate at which the hydrogen is
produced, and so the cell becomes polarized; but it soon recovers after
a short rest.
The so-called “dry” cells so much used at the present time are not
really dry at all; if they were they would give no current. They are in
fact Leclanché cells, in which the containing vessel is made of zinc
to take the place of a zinc rod; and they are dry only in the sense
that the liquid is taken up by an absorbent material, so as to form
a moist paste. Dry cells are placed inside closely fitting cardboard
tubes, and are sealed up at the top. Their chief advantage lies in
their portability, for as there is no free liquid to spill they can be
carried about and placed in any position.
Public-domain text, read in full here on John Shaqi.
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