It is a curious fact in nature that two such substances as chlorine and
sodium, both of them so difficult and dangerous to handle, should unite
together to form such a useful and harmless compound as common salt. The
important element in bleaching-powder is the chlorine which it contains.
It is extensively used in the manufacture of paper and in all other
materials where bleaching is required. The object of combining it with
lime, forming a chloride of lime, is simply to have a convenient method
of holding the chlorine in a safe and convenient manner until it is
needed for use.
The chemical works at Niagara Falls manufacture bleaching-powder on a
very large scale. The part that electricity plays is to separate the
chlorine from the sodium as it exists in common salt. At the works I was
first taken into a room where a large quantity of salt was stored. A
belt with little carrier-buckets on it picked up this salt and carried
it into another room, where it was thrown into a vast mixing-vat
containing water. The salt was mixed with water until a saturated
solution was obtained. In a large room, covering one-half acre or more
of ground, were assembled a great number of shallow vessels, about 4 by
5 feet square and 1 foot deep. These vessels were sealed up so that they
were gas-tight. Communicating with all of these vessels were pipes
connecting with the great tank containing the saturated solution of
salt.
From the top or cover of each vessel is a pipe running to a main pipe
that carries off the chlorine gas into another room as fast as it is
formed. Through each one of these vessels a current of electricity
passes; the whole system consuming about 2000 horse-power. The electric
current, as it passes through the brine, separates the chlorine from the
sodium, the chlorine passing in the form of gas up through the pipes,
before mentioned, into the main pipe, where it is carried into another
large room and discharged into a system of gas-tight chambers. Upon the
floor of these chambers is spread a coating of unslacked lime ground
into a fine powder. The lime has a strong affinity for the chlorine gas
and rapidly absorbs it, forming chloride of lime. When the lime is fully
saturated with the chlorine the gas is turned off from that chamber,
which is then opened up and the chloride taken out for shipment. A new
coating of lime is now spread in the chamber and the gas is turned on
and the process repeated.
There are a number of these chambers, so that the operation in all of
its phases is going on continuously. The room where the chlorine gas is
formed is thoroughly ventilated, a precaution which is very necessary in
case any one of the vats should spring a leak, as they sometimes do.
Public-domain text, read in full here on John Shaqi.
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