Elements of Agricultural ChemistryAnderson, Thomas
Science
Elements of Agricultural Chemistry
Anderson, Thomas
Agricultural chemistry
It is important to observe that when a salt is used, the base only is
absorbed, and the acid escapes in combination with lime; even nitric
acid, notwithstanding its importance as a food of plants, being in this
predicament. From this it may be gathered that lime is not readily
absorbed from solutions of its salts; indeed, it would appear that the
only salt of that substance liable to absorption is the bicarbonate,
from which it is taken to the extent of 1.4 per cent by the soil. The
absorption of lime from this salt, and that of phosphoric acid, which
takes place to a considerable extent, probably occurs, however, quite
independently of the clay present in the soil, and is occasioned by its
_lime_, which forms an insoluble compound with phosphoric acid, and by
removing half the carbonic acid of the bicarbonate of lime converts it
also into an insoluble state.
In addition to these mineral substances, organic matters are also
removed from solution. This is conspicuously seen in the case of putrid
urine, which not only loses its ammonia, but also its smell and colour,
when allowed to percolate through soil; and an equally marked result was
obtained with flax water, from which the organic matter was entirely
abstracted.
The cause of this absorptive power is still very imperfectly known. Mr.
Way having observed that sand has no such property, while clay, even
when obtained from a considerable depth, always possesses it, supposed
that the absorption was entirely due to that substance. A difficulty,
however, presents itself in explaining how it should happen that while a
pure clay absorbs only 0.2847 of ammonia, a loamy soil, of which
one-half probably is sand, should absorb a larger quantity. The
inference is, that the effect cannot be due to the clay as a whole, and
Mr. Way has sought to explain it by supposing that there exist in the
soil particular double silicates of alumina and lime. He has shown that
felspar and the other minerals from which the soil is produced have no
absorbent power, but that artificial compounds can be formed which act
upon solutions of ammonia and potash in a manner very similar to the
soil; but there is not the slightest evidence that these compounds exist
in the soil, and in the year 1853[I] I pointed out the probability that
clay is not the only agent at work, but that the organic matters take
part in the process. So powerful indeed is the affinity of these
substances for ammonia, that chemists are at one as to the difficulty of
obtaining humic and other similar acids pure, owing to the obstinacy
with which they retain it; and there cannot be a doubt that in many
soils these substances are in this point of view of much importance.
This is particularly the case in peat soils, which, though naturally
barren, may be made to produce good crops by the application of sand or
gravel; and as neither of these can cause any absorption of the valuable
matters, we must attribute this effect to the organic matter. Referring
Public-domain text, read in full here on John Shaqi.
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