Elements of Agricultural ChemistryAnderson, Thomas
Science
Elements of Agricultural Chemistry
Anderson, Thomas
Agricultural chemistry
to an earlier series of experiments made in 1850, I showed that, if a
quantity of dry peat be taken and ammonia poured on it, its smell
disappears; and this may be continued until upwards of 1.5 per cent of
dry ammonia has been absorbed, and this quantity is _retained_ by the
peat.
In this case pure ammonia was used, but Way's experiments having shown
that this alkali is not absorbed from its salts by organic matters, I
expressed the opinion that humate of lime (which certainly exists in
most soils) ought on chemical grounds to decompose the salts of ammonia
and cause the retention of their base. The recent researches of
Brustlein have shown that lime does cause the organic matters to absorb
ammonia from its salts. He confirms the fact that pure ammonia is
absorbed by peat, and shows that decayed wood has the same effect,
although both are without action on solutions of its salts. A stiff
clay, on the other hand, containing organic matters and much carbonate
of lime, readily absorbed ammonia, both when pure and combined; but
after extracting the lime by means of a dilute acid, it lost the power
of taking it from its salts, although it retained the free alkali as
completely as before. On the addition of a small quantity of lime, it
again acquired the power of withdrawing ammonia from its compounds.
These experiments may be explained, either on the supposition of the
presence of humate of lime, or by supposing that the carbonate of lime
first decomposed the salts of ammonia, and that the liberated alkali
combined with the organic matter. It must be admitted, however, that it
is very doubtful whether the ammonia and other substances are fixed in
the soil by a true chemical combination. They are certainly retained by
a very feeble attraction, for it appears from Brustlein's experiments
that ammonia may be, to a considerable extent, removed by washing with
abundance of water, and that if the soil which has absorbed ammonia be
allowed to become dry in the air, it loses half its ammonia, and after
four times moistening and drying, three-fourths have disappeared. These
facts are certainly not incompatible with the presence of a true
chemical compound, for the humate of ammonia is not absolutely
insoluble, and many cases occur of actions taking place in the presence
of water, which are entirely reversed when that fluid is removed; and it
is quite possible that when humate of ammonia is dried in contact with
carbonate of lime, it may be decomposed, and carbonate of ammonia
escape. There are other circumstances, however, which render it, on the
whole, most probable that the combination is not wholly chemical, but
rather of a physical character, among which may be more especially
mentioned the fact, that the quantity of the substances retained by the
soil is dependent on the degree of dilution of the fluid from which they
are taken; and that the quantity absorbed never exceeds a very small
fraction of the weight of the soil.
Public-domain text, read in full here on John Shaqi.
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