Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
That the metals cannot be dissolved in acids without being previously
oxydated, or by procuring oxygen, for that purpose, from the acids
during solution, is a general and well established fact, which I have
perhaps repeated too often. Hence, as sulphurous acid is already
deprived of great part of the oxygen necessary for forming the sulphuric
acid, it is more disposed to recover oxygen, than to furnish it to the
greatest part of the metals; and, for this reason, it cannot dissolve
them, unless previously oxydated by other means. From the same principle
it is that the metallic oxyds dissolve without effervescence, and with
great facility, in sulphurous acid. This acid, like the muriatic, has
even the property of dissolving metallic oxyds surcharged with oxygen,
and consequently insoluble in sulphuric acid, and in this way forms true
sulphats. Hence we might be led to conclude that there are no metallic
sulphites, were it not that the phenomena which accompany the solution
of iron, mercury, and some other metals, convince us that these metallic
substances are susceptible of two degrees of oxydation, during their
solution in acids. Hence the neutral salt in which the metal is least
oxydated must be named _sulphite_, and that in which it is fully
oxydated must be called _sulphat_. It is yet unknown whether this
distinction is applicable to any of the metallic sulphats, except those
of iron and mercury.
TABLE _of the Combinations of Phosphorous and Phosphoric Acids, with the
Salifiable Bases, in the Order of Affinity._
_Names of the_ _Names of the Neutral Salts formed by_
_Bases._ _Phosphorous Acid,_ _Phosphoric Acid._
Phosphites of(B) Phosphats of(C)
Lime lime lime.
Barytes barytes barytes.
Magnesia magnesia magnesia.
Potash potash potash.
Soda soda soda.
Ammoniac ammoniac ammoniac.
Argill argill argill.
Oxyds of(A)
zinc zinc zinc.
iron iron iron.
manganese manganese manganese.
cobalt cobalt cobalt.
nickel nickel nickel.
lead lead lead.
tin tin tin.
copper copper copper.
bismuth bismuth bismuth.
antimony antimony antimony.
arsenic arsenic arsenic.
mercury mercury mercury.
silver silver silver.
gold gold gold.
platina platina platina.
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