Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Though a Volatile Alkali be constantly the result of putrefaction, yet
it must not therefore be imagined that none can be produced by any
other means; on the contrary, most of those substances which contain
the ingredients necessary to form it, yield no inconsiderable quantity
thereof in distillation. Tartar, for example, which by being burnt in
an open fire is converted, as was shewn, into a Fixed Alkali, yields a
Volatile Alkali when it is decomposed in close vessels; that is, when
it is distilled; because, in this latter case, the oily part is not
dissipated or burnt, as it is by calcination in a naked fire, but has
time to unite with some of the earth and acid of the mixt, in such a
manner as to form a true Volatile Alkali.
To prove that on this occasion, as well as on all others, where
unputrefied bodies yield a Volatile Alkali, this salt is the product of
the fire, we need only observe, that in these distillations it never
rises till after some part of the phlegm, of the acid, and even of the
thick oil of the mixt, is come over; which never is the case when it is
formed beforehand in the body which is the subject of the operation, as
it is in those which have undergone putrefaction: for this salt, being
much lighter and more volatile than those other substances, rises of
course before them in distillation.
CHAP. XVI.
_A General View of_ CHYMICAL DECOMPOSITION.
Though we have considered all the substances which enter into the
composition of Vegetables, Animals, and Minerals, whether as primary or
as secondary principles, it will not be improper to shew in what order
we obtain these principles from the several mixts; and especially from
Vegetables and Animals, because they are much more complicated than
Minerals. This is called _Analysing_ a compound.
The method most commonly taken to decompose bodies is by applying to
them successive degrees of heat, from the gentlest to the most violent,
in appropriated vessels, so contrived as to collect what exhales from
them. By this means the principles are gradually separated from each
other; the most volatile rise first, and the rest follow in order, as
they come to be acted on by the proper degree of heat: and this is
called _Distillation_.
But it being observed that fire, applied to the decomposition of
bodies, most commonly alters their secondary principles very sensibly,
by combining them in a different manner with each other, or even partly
decomposing them, and reducing them to their primitive principles;
other means have been used to separate those principles without the
help of fire.
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