Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This oily substance is often found combined with Volatile Alkalis in
such a large proportion as to disguise it, in some measure, and render
it exceedingly foul. The salt may be freed from its superfluous oil by
repeated sublimations; and particularly by subliming it from absorbent
earths, which readily drink up oils. This is called the _Rectification_
of a Volatile Alkali. The salt, which before was of a yellowish or
dirty colour, by being thus rectified becomes very white, and acquires
an odour more pungent and less fetid than it had at first, that is,
when obtained by one single distillation from a putrid substance.
It is proper to observe, that the rectification of a Volatile Alkali
must not be carried too far, or repeated too often; for by that means
it may be entirely decomposed at length; and particularly if an
absorbent earth, and especially chalk, be employed for that purpose,
the salt may be converted into an oil, an earth, and water.
Volatile Alkalis act upon several metallic substances, and particularly
on copper; of which they make a most beautiful blue solution. On this
property depends a pretty singular effect, which happens sometimes when
we attempt, by means of a Volatile Alkali, to separate copper from
any acid with which it is combined. Instead of seeing the liquor grow
turbid, and the metal fall, both which generally happen when any Alkali
whatever is mixed with a metallic solution, we are surprised to observe
the solution of copper, upon adding a Volatile Alkali, retain its
limpidity, and let fall no precipitate; or at least, if the liquor does
grow turbid, it remains so but for a moment, and instantly recovers its
transparency.
This is occasioned by adding such a quantity of Volatile Alkali as
is more than sufficient fully to saturate the acid of the solution,
and considerable enough to dissolve all the copper as fast as it is
separated from the acid. On this occasion the liquor acquires a deeper
blue than it had before; which arises from the property which Volatile
Alkalis have of giving this metal, when combined with them, a fuller
blue than any other solvent can: hence we have a touchstone to discover
copper wherever it is; for let the quantity of this metal combined
with other metals be ever so small, a Volatile Alkali never fails to
discover it, by making it appear of a blue colour.
Public-domain text, read in full here on John Shaqi.
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