Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Fixed alkalis are also well qualified to absorb the sulphur of cinabar.
Cinabar must be decomposed in close vessels, and by the way of
distillation; otherwise the mercury, as soon as it separates from the
sulphur, will be dissipated in vapours and entirely lost.
In this operation it is needless to add either flux or phlogiston;
because the cinabar is decomposed without melting, and the mercury,
though in a mineral state, contains, like gold and silver, all the
phlogiston requisite to secure its metalline properties.
_Of the Ores of Regulus of Antimony._
Regulus of Antimony is always found in a mineral state: it is
mineralized by sulphur; but sometimes, though rarely, it is also
combined with a little arsenic.
When the ore of regulus of antimony is to be decomposed, the first
thing to be done is to expose it to a degree of heat too weak to melt
its earthy and stony parts, but strong enough to fuse its reguline,
together with its sulphureous parts, which by this means are separated
from the earth, and united into one mass, known by the name of Antimony.
It is plain that this first operation, which is founded on the great
fusibility of antimony, produces, with regard to the ore of regulus
of antimony, the same effect that washing hath on other ores: so that
after this first fusion nothing more is requisite to the obtaining of
a pure regulus of antimony, but to separate it from its sulphur by
roasting, and to melt it with some matter abounding in phlogiston,
in the same manner as other metallic matters are treated. The term
_Calcination_ is generally used to express this torrefaction of
antimony, by means whereof the metallic earth of the regulus of
antimony is separated from its sulphur.
As regulus of Antimony hath, like Mercury, much less affinity with
sulphur than the other metals have, it follows that antimony may be
decomposed by the same means as cinabar; but the regulus, so obtained,
is adulterated with a portion of the additament made use of, which
combines therewith.
There is still another process employed for obtaining the regulus of
antimony: it consists, as was mentioned in its place, in detonating
the mineral with a mixture of nitre and tartar, applied in such a
proportion that, after the detonation has consumed the sulphur, there
may remain so much inflammable matter as will be sufficient to furnish
the metalline earth of the antimony with the phlogiston necessary to
preserve its metallic properties. But by this method less regulus is
produced, than by calcining, or torrefying, and reducing as usual.
_Of the Ores of Bismuth._
Public-domain text, read in full here on John Shaqi.
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