Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The ore of Bismuth consists of the semi-metal mineralized by arsenic,
and of an unmetallic earth. It is very easy to decompose this ore,
and to extract the bismuth it contains: for this purpose it need only
be exposed to a moderate heat, whereby the arsenic will be dissipated
in vapours, and the bismuth melted, which will then separate from the
unmetallic earth. This earth, at least, in several ores of bismuth,
possesses the property of tinging all vitrifiable matters, with which
it is melted, of a beautiful blue colour.
To decompose the ore of bismuth no flux or inflammable matter is used;
because this semi-metal is possessed, even in its mineral state, of
all the phlogiston requisite to maintain its metalline properties; and
its great fusibility makes it unnecessary to melt the unmetallic earth
contained in its ore.
_Of the Ores of Zinc._
Zinc is not generally obtained from a particular ore of its own; but
sublimes during the fusion of a mineral, or rather a confused mass of
minerals, that contains this semi-metal together with iron, copper,
lead, sulphur, arsenic, and, like all other ores, an unmetallic earth.
Nevertheless, there is a substance which may be considered as the
proper ore of zinc, because it contains a pretty large quantity of
that semi-metal, a little iron, and an unmetallic earth. It is called
_Calamine_, or _Lapis Calaminaris_; but hitherto the art of procuring
zinc directly from this mineral hath no where been practised. Calamine
is commonly employed only to convert copper into brass, or a yellow
metal, by cementing it therewith. Indeed, till lately, no easy or
practicable method of obtaining pure zinc from calamine was publicly
known; for that semi-metal being volatile and very inflammable, its ore
cannot be fused like others. Mr. Margraaf was the first who, by mixing
powdered charcoal with calamine in close vessels, obtained a perfect
zinc from it, by the means of distillation or sublimation, as shall be
shewn in our Practical Chymistry.
_Of Arsenical Minerals._
Arsenic, as well as sulphur, is naturally combined with almost all
ores, or minerals containing metallic substances. As it is very
volatile, while the matters with which it is united are fixed, at least
in comparison therewith, it is easily separated by sublimation.
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