Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The minerals that contain most arsenic are the white pyrites, orpiment,
and cobalt. We have already considered the white pyrites: as to
orpiment, it consists of sulphur and arsenic. Both these substances
being very volatile, it is difficult to separate them by sublimation:
yet, with proper management, and a due regulation of the fire, this
separation may be effected; because sulphur sublimes a little more
easily than arsenic. But it is more convenient, as well as more
expeditious, to make use of some additament that hath a greater
affinity with one of those substances than with the other. Fixed
alkalis and mercury, both of which have more affinity with sulphur than
with arsenic, may be very properly employed on this occasion.
Cobalt is a mineral composed of arsenic, an unmetallic earth, and
frequently bismuth: and as none of these are very volatile, except the
arsenic, this may be easily separated from the rest by sublimation. The
unmetallic earth which remains has, like that of the ore of bismuth,
the property of giving a blue colour to any vitrifiable matters
melted with it; whence it is conjectured, that cobalt and the ore
of bismuth have a great resemblance, or are often blended with each
other. Nevertheless, Mr. Brant, an ingenious Swedish Chymist, insists
that they are very different: he pretends that the metallic substance
contained in the true cobalt is a semi-metal of a peculiar nature,
which hath been erroneously confounded with bismuth: and indeed he
proves by a great number of curious experiments, related in the Memoirs
of the Academy of Upsal, that these two metallic substances have
properties that are essentially different: to that which is obtained
from cobalt, he gives the name of _Regulus of Cobalt_.
Besides the minerals already recited, there is found in the bowels of
the earth another species of compound body, of which we have already
taken notice; but which is supposed, with some degree of probability,
to belong as much to the vegetable as to the mineral kingdom: I mean
the _Bitumens_; which the best observations oblige us to consider as
vegetable oils, that by lying long in the earth have contracted an
union with the mineral acids, and by that means acquired the thickness,
consistence, and other properties observable in them.
By distillation they yield an oil, and an acid not unlike a mineral
acid. Mr. Bourdelin has even demonstrated, by a very artful and
ingenious process, that amber contains a manifest acid of sea-salt. See
the Memoirs of the Royal Academy of Sciences.
CHAP. XVII.
_Explanation of the Table of Affinities_.
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