Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The upper line of Mr. Geoffroy's Table, comprehends several substances
used in Chymistry. Under each of those substances are ranged in
distinct columns several matters compared with them, in the order
of their relation to that first substance; so as that which is the
nearest to it is that which hath the greatest affinity with it, or that
which none of the substances standing below it can separate therefrom;
but which, on the contrary, separates them all when they are combined
with it, and expels them in order to join itself therewith. The same is
to be understood of that which occupies the second place of affinity;
that is, it has the same property with regard to all below it, yielding
only to that which is above it: and so of all the rest.
At the top of the first column stands the character which denotes an
Acid in general. Immediately under this stands the mark of a Fixed
Alkali, being placed there as the substance which has the greatest
affinity with an Acid. After the Fixed Alkali appears the Volatile
Alkali, whose affinity with Acids yields only to the Fixed Alkali.
Next come the Absorbent Earths; and last of all Metallic Substances.
Hence it follows, that when a Fixed Alkali is united with an acid it
cannot be separated therefrom by any other substance; that a Volatile
Alkali united with an Acid cannot be separated from it by any thing
but a Fixed Alkali; that an Absorbent Earth combined with an acid
may be separated from it either by a Fixed or by a Volatile Alkali;
and lastly, that any Metallic Substance combined with an Acid may be
separated from it by a Fixed Alkali, a Volatile Alkali, or an Absorbent
Earth.
There are many important remarks to be made on this first column.
First, it is making the rule too general to say that any Acid whatever
has a greater affinity with a Fixed Alkali, than with any other
substance. And indeed Mr. Geoffroy himself hath made an exception
with respect to the Vitriolic Acid; for in the fourth column, at the
head of which stands that Acid, we find the sign of the Phlogiston
placed above that of the Fixed Alkali, as having a greater affinity
than the Fixed Alkali with the Vitriolic Acid. This is founded on the
famous experiment, wherein Vitriolated Tartar and Glauber's Salt are
decompounded by means of the Phlogiston, which separates the Fixed
Alkalis of these Neutral Salts, and uniting with the Vitriolic Acid
contained in them forms therewith a Sulphur.
Public-domain text, read in full here on John Shaqi.
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