Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Secondly, Nitre deflagrates, and is decomposed, by the contact of any
inflammable matter whatever that is actually ignited; and the operation
which produces Phosphorus is no other than a decomposition of sea-salt,
whose Acid quits its Alkaline basis to join with the Phlogiston: now
these facts furnish very strong reasons for believing that both these
Acids, as well as the Vitriolic, have a stronger affinity with the
Phlogiston than with a Fixed Alkali. Lastly, as several experiments
shew the Vegetable Acids to be only the Mineral Acids disguised and
mortified, there are sufficient grounds for suspecting that Acids in
general have a greater affinity with the Phlogiston than with Fixed
Alkalis: so that instead of making an exception with regard to the
Vitriolic Acid, it would perhaps be better to lay down this greater
affinity as common to all Acids whatever, and to place the Phlogiston
in the first column, immediately under the character which denotes an
Acid in general. This theory, however, stands in need of confirmation
from other experiments[4].
[4] Mr. Margraaf, an able German Chymist, has made several
experiments, which induce him to think that the Acid of Phosphorus
is of a particular kind, and different from that of sea-salt. May it
not be the Marine Acid, but altered by the union it has contracted
with the Phlogiston? Or may it not be, with respect to Phosphorus,
what the volatile sulphureous spirit is, with respect to Sulphur?
See the Memoirs of the Royal Academy of Sciences of Berlin.
Thirdly, in this same column the character of a Volatile Alkali is set
above that of an Absorbent Earth, as having a greater affinity with
Acids; and yet these Absorbent Earths decompose the Ammoniacal salts,
drive away the Volatile Alkali from the Acids, and assume its place.
This is one of the first objections made against Mr. Geoffroy's Table.
His answer thereto is printed in the Memoirs of the Academy of Sciences
for 1718, where his Table also is to be found. We have already declared
our opinion about this matter in treating of a Volatile Alkali.
Fourthly, in 1744, Mr. Geoffroy, brother to the author of the Table,
who hath done no less honour to Chymistry than that eminent physician,
gave in a Memoir containing an exception to the last affinity in the
first column; namely, that which places Absorbent Earths above Metallic
substances. He therein shews, that Alum may be converted into Copperas
by boiling it in iron vessels; that, on this occasion, the iron
precipitates the Earth of the Alum, separates it from its Acid, and
assumes its place; so that of course it must have a greater affinity,
than the Absorbent Earth of Alum, with the Vitriolic Acid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account