Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
At the head of the second column stands the character of the Marine
Acid, which signifies that the affinities of this Acid are the subject
of the column. Immediately below it is placed the mark of Tin. As this
is a metalline substance, and as the first column places metalline
substances in the lowest degree of affinity with all Acids, it is
plain we must suppose Fixed Alkalis, Volatile Alkalis, and Absorbent
Earths, to be placed here in order after the Marine Acid, and before
Tin. Tin, then, is of all Metalline substances that which has the
greatest affinity with the Marine Acid; and then follow Regulus of
Antimony, Copper, Silver, Mercury. Gold comes last of all; and there
are no less than two vacant places above it. By this means it is in
some sort excluded from the rank of substances that have an affinity
with the Marine Acid. The reason thereof is, that this Acid alone is
not capable of dissolving Gold and combining therewith, necessarily
requiring for that purpose the aid of the Nitrous Acid, or at least of
the Phlogiston.
The third column exhibits the affinities of the Nitrous Acid, the
character whereof stands at its head. Immediately below it is the sign
of Iron, as the metal which has the greatest affinity with this Acid;
and then follow other metals, each according to the degree of its
relation; to wit, Copper, Lead, Mercury, and Silver. In this column,
as in the preceding one, we must suppose the substances, which in the
first column stand above Metallic substances, to be placed in their
proper order before Iron.
The fourth column is intended to represent the Affinities of the
Vitriolic Acid. Here Mr. Geoffroy has placed the Phlogiston as the
substance which has the greatest affinity with this Acid, for the
reason given in our explanation of the first column. Below it he has
ranked Fixed Alkalis, Volatile Alkalis, and Absorbent Earths, to
shew that this is an exception to the first column. As to Metalline
substances, he has set down but three, being those with which the
Vitriolic Acid has the most perceptible affinity: these metals, placed
in the order of their affinities, are Iron, Copper, and Silver.
The fifth column shews the affinities of Absorbent Earths. As these
Earths have no sensible affinity but with Acids, this column contains
only the characters of the Acids ranked according to the degree of
their strength, or affinity with the Earths; to wit, the Vitriolic, the
Nitrous, and the Marine Acids. Underneath this last might be placed the
Acid of Vinegar, or the Vegetable Acid.
The sixth column expresses the Affinities of Fixed Alkalis with Acids,
which are the same with those of Absorbent Earths. Moreover, we find
Sulphur placed here below all the Acids; because Liver of Sulphur,
which is a combination of Sulphur with a Fixed Alkali, is actually
decompounded by any Acid: for any Acid precipitates the Sulphur and
unites with the Alkali.
Public-domain text, read in full here on John Shaqi.
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