Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Put all these waters together into a glass vessel that widens upwards;
set it on a sand-bath, and heat the liquor till a considerable smoke
arises; but take care not to make it boil. Continue the same degree of
fire till the surface of the liquor begins to look dim, as if some
dust had fallen into it; then cease evaporating, and remove the vessel
into a cool place: in the space of four and twenty hours will be formed
therein a quantity of crystals, of a green colour and a rhomboidal
figure: these are Vitriol of Mars, or Copperas. Decant the remaining
liquor; add thereto twice its weight of water; filter, evaporate, and
crystallize as before; repeat these operations till the liquor will
yield no more crystals, and keep by themselves the crystals obtained at
each crystallization.
_OBSERVATIONS._
The Pyrites are minerals which, by their weight and shining colours,
frequently impose on such as are not well acquainted with ores. At
first sight they may be taken for very rich ones; and yet they consist
only of a small quantity of metal combined with much sulphur or
arsenic, and sometimes with both.
They strike fire with a steel as flints do, and emit a sulphureous
smell: so that they may be known by this extemporaneous proof. The
metal most commonly and most abundantly found in the Pyrites is iron;
the quantity whereof sometimes equals, or even exceeds, that of the
sulphur. Besides metallic and sulphureous matters, the Pyrites contain
also some unmetallic earth.
There are several sorts of Pyrites: some of them contain only iron and
arsenic. They have not all the property of efflorescing spontaneously
in the air, and turning into vitriol: none do so but such as consist
only of iron and sulphur, or at least contain but a very small portion
of copper, or of arsenic: and even amongst those that are composed of
iron and sulphur alone, there are some that will continue for years
together exposed to the air without shooting, and indeed without
suffering the least sensible alteration.
The efflorescence of the Iron Pyrites, and the changes they undergo,
are phenomena well worth our notice. They depend on the singular
property which iron possesses of decomposing sulphur by the help of
moisture. If very fine iron-filings be accurately mingled with flowers
of sulphur, this mixture, being moistened with water, grows very hot,
swells up, emits sulphureous vapours, and even takes fire; what remains
is found converted into Vitriol of Mars. On this occasion, therefore,
the sulphur is decomposed; its inflammable part is dissipated or
consumed; its acid combines with the iron, and a Vitriol arises from
that conjunction.
This is the very case with the Pyrites that consist only of iron
and sulphur; yet some of them, as we said before, do not effloresce
spontaneously and turn to Vitriol. The reason probably is, that, in
such minerals, the particles of iron and sulphur are not intimately
mixed together, but separated by some earthy particles.
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