Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In order to procure Vitriol from Pyrites of this kind, they must be
for some time exposed to the action of fire, which, by consuming part
of their sulphur, and rendering their texture less compact, makes way
for the air and moisture, to which they must be afterwards exposed, to
penetrate their substance, and produce in them the changes with which
those others are affected that germinate spontaneously.
The Pyrites which contain copper and arsenic, and for that reason
do not effloresce, must likewise undergo the action of fire; which,
besides the effects it produces on Pyrites that consist of iron and
sulphur only, dissipates also the greatest part of the arsenic. These
Pyrites being first roasted, and then exposed to the air for a year or
two, do also yield Vitriol; but then it is not a pure Vitriol of Iron,
but is combined with a portion of blue Vitriol, the basis of which is
Copper.
Sometimes also there is Alum in the vitriolic waters drawn off the
Pyrites. It was on account of this mixture of different salts that we
recommended the keeping apart the crystals obtained from each different
crystallization: for by this means they may be examined separately, and
the species to which they belong discovered.
When Vitriol of Iron is adulterated with a mixture of the Vitriol
of Copper only, it is easy to purify it and bring it to be entirely
martial, by dissolving it in water, and setting plates of iron in the
solution: for iron having a greater affinity than copper with the
vitriolic acid, separates the latter from it, and assuming its place
produces a pure Vitriol of Mars.
In large works for extracting Vitriol from the Pyrites they proceed
thus. They collect a great quantity of Pyrites on a piece of ground
exposed to the air, and pile them up in heaps of about three feet high.
There they leave them exposed to the action of the air, sun, and rain,
for three years together; taking care to turn them every six months,
in order to facilitate the efflorescence of those which at first lay
undermost. The rain-water which has washed those Pyrites is conveyed by
proper channels into a cistern; and when a sufficient quantity thereof
is gathered, they evaporate it to a pellicle in large leaden boilers,
having first put into it a quantity of iron, some part of which is
dissolved by the liquor, because it contains a vitriolic acid that is
not fully saturated therewith. When it is sufficiently evaporated, they
draw it off into large leaden or wooden coolers, and there leave it to
shoot into crystals. In these last vessels several sticks are placed,
crossing each other in all manner of directions, in order to multiply
the surfaces on which the crystals may fasten.
Public-domain text, read in full here on John Shaqi.
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