Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When it is obtained by distillation, if the matters from which you
extract it contain moreover some other minerals of nearly the same
volatility, such, for instance, as Arsenic, or Mercury, these minerals
will come over with it. This is easily perceived: for pure sublimed
Sulphur is always of a beautiful yellow, inclining to a lemon colour.
If it look red, or have a reddish cast, it is a sign that some Arsenic
hath risen along with it.
Mercury sublimed with Sulphur likewise gives it a red colour; but
Sulphur is very seldom adulterated with this metallic substance: for
Arsenic is frequently found combined with the Pyrites, and other
sulphureous minerals; whereas, on the contrary, we very rarely meet
with any Mercury in them.
But if Mercury should happen to rise with the Sulphur in distillation,
it may be discovered by examining the sublimate; which, in that case,
will have the properties of Cinabar: on being broken its inside will
appear to consist of needles adhering laterally to each other; its
weight will be very considerable; and, lastly, the great heat of the
place where it is collected will furnish another mark to know it by;
for, as Cinabar is less volatile than Arsenic or Sulphur, it fastens on
places too hot for either Sulphur or Arsenic to bear.
Sulphur may also be adulterated with such fixed matters, either
metallic or earthy, as it may have carried up along with it in the
distillation, or as may have been sublimed by the Arsenic, which has a
still greater power than Sulphur to volatilize fixed bodies.
If you desire to free the Sulphur from most of these heterogeneous
matters, it must be put into an earthen cucurbit, and set in a
sand-bath. To the cucurbit must be fitted one or more aludels, and such
a degree of heat applied as shall but just melt the Sulphur; which is
much less than that necessary to separate the Sulphur from its matrix.
As soon as the Sulphur is melted it will sublime in lemon-coloured
flowers, that will stick to the insides of the aludels.
When nothing more appears to rise with this degree of heat, the vessels
must be suffered to cool. At the bottom of the cucurbit will be found
a sulphureous mass, containing the greatest part of the adventitious
matters that were mixed with the Sulphur, and more or less red or
dark-coloured, according to the nature of those matters.
When we come to treat of Arsenic and Mercury, we shall give the methods
of separating Sulphur entirely from those metallic substances.
PROCESS III.
_To extract Alum from aluminous Minerals._
Take such minerals as are known or suspected to contain Alum. Expose
them to the air, that they may effloresce. If they remain there a year
without any sensible change, calcine them, and then leave them exposed
to the air, till a bit thereof being put on the tongue imparts an
astringent aluminous taste.
Public-domain text, read in full here on John Shaqi.
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