Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When your matters are thus prepared, put them into a leaden or glass
vessel; pour upon them thrice their weight of hot water; boil the
liquor; filter it; and repeat these operations till the earth be so
edulcorated that the water which comes off it hath no taste. Mix all
these solutions together, and let them stand four and twenty hours,
that the gross and earthy parts may settle to the bottom; or else
filter the liquor: then evaporate till it will bear a new-laid egg. Now
let it cool, and stand quiet four and twenty hours: in that time some
crystals will shoot, which are most commonly vitriolic; for Alum is
rarely obtained by the first crystallization. Remove these vitriolic
crystals: if any crystals of Alum be found amongst them, these must be
dissolved anew, and set to crystallize a second time in order to their
purification; because they partake of the nature as well as of the
colour of vitriol. By this method extract all the Alum that the liquor
will yield.
If you get no crystals of Alum by this means, boil your liquor again,
and add to it a twentieth part of its weight of a strong alkaline
lixivium, or a third part of its weight of putrefied urine, or a small
quantity of quick-lime. Experience and repeated trials must teach you
which of these three substances is to be preferred, according to the
particular nature of the mineral on which you are to operate. Keep
your liquor boiling, and if there be any alum in it, there will appear
a white precipitate: in that case let it cool and settle. When the
white precipitate is entirely fallen, decant the clear, and leave the
crystals of Alum to shoot at leisure, till the liquor will yield no
more: it will then be exceeding thick.
_OBSERVATIONS._
Alum is obtained from several sorts of Minerals. In some parts of
Italy, and in sundry other places, it effloresces naturally on the
surface of the earth. There it is swept together with brooms, and
thrown into pits full of water. This water is impregnated therewith
till it can dissolve no more. Then it is filtered, and set to evaporate
in large leaden vessels; and when it is sufficiently evaporated, and
ready to shoot into crystals, it is drawn off into wooden coolers, and
there left for the salt to crystallize.
In aluminous soils there are often found springs strongly impregnated
with Alum: so that to obtain it, the water need only be evaporated.
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