Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
But because Alkalis decompound also those Neutral salts which have an
earth for their basis, care must be taken that too much thereof be not
added; else what you put in, more than is necessary to decompound the
vitriolic salts in your liquor, will attack the Alum, and decompound it
likewise.
The Alkali made use of to promote the crystallization of the Alum
joins with the Vitriolic Acid, which had dissolved the substances now
precipitated, and therewith forms different Neutral salts according
to its particular nature. If the Alkali be a lixivium of common
wood-ashes, the Neutral salt will be a vitriolated Tartar; if a
lixivium of the ashes of a maritime plant like Soda, the Neutral salt
will be a Glauber's salt; if putrefied urine, the Neutral salt will be
a vitriolic Ammoniacal salt. Some of these salts incorporate with the
Alum, which in large works crystallizes in vast lumps: and hence it
comes that some sorts of Alum when mixed with a fixed Alkali smell like
a volatile Alkali.
The crystals of Alum are octaedral, that is, they are solids with eight
sides. These octaedral solids are triangular pyramids, having their
angles cut away, so that four of their surfaces are hexagons, and the
other four triangles.
Sulphur, Vitriol, and Alum are the three principal subjects in which
we certainly know that the universal or Vitriolic Acid particularly
resides, and from which we extract it when we want to have it pure. For
this reason we thought it proper, before we treated of the extraction
of this Acid, to shew the method of separating those matters themselves
from the other minerals out of which we obtain them.
Moreover, all the other matrices, in which the Vitriolic Acid is most
commonly lodged, may be referred to one or other of the matters which
serve as bases to these three minerals.
To Sulphur we may refer all combinations of the Vitriolic Acid with an
inflammable matter: but we must take care not to confound Sulphur with
those Bitumens in which the Vitriolic Acid may be found: for the basis
of those bitumens is a real Oil; whereas the basis of Sulphur is the
pure Phlogiston. Yet as Oils themselves contain the Phlogiston, which,
in union with the Vitriolic Acid forms a true Sulphur, it follows that
such bitumens may in a certain respect be classed with Sulphur.
The same is to be said of Vitriol. The name is usually given to such
combinations only as are formed of the Vitriolic Acid with Iron or
Copper, which make the green and blue Vitriol; and to a third species
of Vitriol, which is white, and has Zinc for its basis: but as the
Vitriolic Acid may, by particular combinations, be united with many
other metallic substances, all such Metallic Salts must be referred to
the class of Vitriols.
The same may also be said of Alum, which is no other than a combination
of the Vitriolic Acid with a particular kind of absorbent earth; so
that all combinations of this Acid with any earth whatever may be
placed in the same class.
Public-domain text, read in full here on John Shaqi.
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