Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In the country about Rome there is a very hard stone, which is hewn out
of the quarry just like other stones for building; this stone yields
a great deal of Alum. In order to extract it, the stones are calcined
for twelve or fourteen hours; after which they are exposed to the air
in heaps, and carefully watered three or four times a-day for forty
days together. In that time they begin to effloresce, and to throw out
a reddish matter on their surface. Then they are boiled in water, which
dissolves all the Alum they contain, and, being duly evaporated, gives
it back in crystals. This is the Alum called _Roman Alum_.
Several sorts of Pyrites also yield a great deal of Alum. The English
have a stone of this kind, which, in colour, is very like a slate. This
stone contains much Sulphur, which they get rid of by roasting it.
After this they steep the calcined stone in water, which dissolves the
Alum it contains, and to this solution they add a certain quantity of a
lye made of the ashes of sea-weeds.
The Swedes have a Pyrites of a bright golden colour, variegated with
silver spots, from which they procure Sulphur, Vitriol, and Alum. They
separate from it the Sulphur and the Vitriol by the methods above
prescribed. When the liquor which hath yielded Vitriol is become thick,
and no more vitriolic crystals shoot in it, they add an eighth part of
its weight of putrefied urine, mixed with a lye made of the ashes of
green wood. Upon this there appears and falls to the bottom a copious
red sediment. They decant the liquor from this precipitate, and, when
it is duly evaporated, find it shoot into beautiful crystals of Alum.
What hath been said, concerning the several matrices from which Alum
is obtained, sufficiently shews, that it is seldom solitary in the
waters with which aluminous subjects have been lixiviated. It is almost
always accompanied with a certain quantity of Vitriol, or other saline
mineral matters, which obstruct its crystallization, and prevent its
being pure. It is with a view to free it from these matters, that the
waters impregnated with Alum are mixed with a certain quantity of the
lye of some fixed Alkali, or with putrefied urine, which contains much
volatile Alkali. These Alkalis have the property of decompounding
all the Neutral salts which have for their basis either an absorbent
earth or a metallic substance; and such as have a metallic substance
for their basis more readily than those whose basis is an earth.
Consequently, if they are mixed with a liquor in which both these sorts
of salts are dissolved, they must decompound that sort whose basis is
metallic sooner than the other whose basis is an earth. This is what
comes to pass in a solution of Alum and Vitriol. The metallic part of
the latter is separated from its acid by the Alkalis when mixed with
that solution; and it is this metallic part, which is generally iron,
that appears in the form of a reddish precipitate, as above-mentioned.
Public-domain text, read in full here on John Shaqi.
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