Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Nitrous Acid is not pure in the earths and stones from which it
is extracted. It is combined partly with the very earth in which
it is formed, and partly with the Volatile Alkali produced by the
putrefaction of the vegetable or animal matters that concurred to its
generation. A Fixed Alkali and Quick-lime are added to the lixivium
of a nitrous earth, in order to decompose the nitrous Salt formed in
that earth, and to separate the Acid from the Volatile Alkali and the
absorbent earth with which it is united: thence comes that copious
sediment which appears in the lye at the beginning of the evaporation.
These matters form with that Acid a true Nitre, much more capable than
the original Nitrous Salts of crystallization, detonation, and the
other properties which are essential thereto. The basis of Nitre is
therefore a Fixed Alkali mixed with a little lime.
The Mother of Nitre, which will yield no more crystals, is brown and
thick: by evaporation over a fire it is further inspissated, and
becomes a dry, solid body; which, however, being left to itself soon
gives, and runs into a liquor. This water still contains a good deal of
Nitre, Sea-salt, and the Acids of these Salts united with an absorbent
earth. It contains moreover a great deal of a fat, viscid matter, which
prevents its crystallizing.
All saline solutions in general, after having yielded a certain
quantity of crystals, grow thick, and refuse to part with any
more, though they still contain much Salt. They are all called
_Mother-waters_, as well as that which hath yielded Nitre. The
Mother-waters of different Salts may prove the subjects of curious and
useful inquiries.
If a Fixed Alkali be mixed with the Mother of Nitre, a copious white
precipitate immediately falls, which being collected and dried is
called _Magnesia_. This precipitate is nothing but the absorbent earth
that was united with the Nitrous Acid, together with a good deal of the
lime that was added, and was also united with that Acid, from which
they are now separated by the Fixed Alkali, according to the usual laws
of affinities.
The Vitriolic Acid poured upon Mother of Nitre causes many Acid vapours
to rise, which are a compound of the Nitrous and Marine Acids, that is,
an _Aqua Regia_. On this occasion also there falls a large quantity of
a white powder, which is still called _Magnesia_; yet it differs from
the former in that it is not, like it, a pure absorbent earth, but
combined with the Vitriolic Acid.
An _Aqua regis_ may also be drawn from nitrous earths by the force of
fire only, without the help of any additament.
PROCESS II.
_To decompose Nitre by means of the Phlogiston. Nitre fixed by
Charcoal._ Clyssus _of Nitre_. Sal Polychrestum.
Public-domain text, read in full here on John Shaqi.
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