Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the solution of Salt-petre has yielded as many crystals of that
Salt as it can yield by cooling, it is again evaporated, and being
then suffered to cool yields more crystals. And thus they continue
evaporating and crystallizing, till the liquor will afford no more
crystals. It is plain that as the Salt-petre crystallizes, the
proportion of Sea-salt to the dissolving liquor increases; and as a
certain quantity of water evaporates also during the time employed in
crystallizing the Salt-petre, a quantity of Sea-salt, proportioned to
the water so evaporating, must crystallize in that time: and this is
the reason why Salt-petre is adulterated with a mixture of Sea-salt.
It likewise follows that the last crystals of Nitre, obtained from a
solution of Salt-petre and Sea-salt, contain much more Sea-salt than
the first.
From all that has been said concerning the crystallization of
Salt-petre and Sea-salt, it is easy to deduce the proper way of
purifying the former of these two Salts from a mixture of the latter.
For this purpose the Salt-petre to be refined need only be dissolved
in fair water. The proportion between the two salts in this second
solution is very different from what it was in the former; for it
contains no more Sea-salt than what had crystallized along with the
Salt-petre under favour of the evaporation, the rest having been left
dissolved in the liquor that refused to yield any more nitrous crystals.
As there is therefore a much greater quantity of Salt-petre than of
Sea-salt in this second solution, it is easy to evaporate it to such a
degree that a great deal of Salt-petre shall crystallize, while much
more of the water must necessarily be evaporated before any of the
Sea-salt will crystallize.
However, the Salt-petre is not yet entirely freed from all mixture of
Sea-salt by this first purification; for the crystals obtained from
this liquor, in which Sea-salt is dissolved, are still encrusted, and,
as it were, infected therewith: hence it comes, that, to refine the
Salt-petre thoroughly, these crystallizations must be repeated four or
five times.
The Salt-petre men commonly content themselves with crystallizing it
thrice, and call the produce Salt-petre of the first, second, or third
shoot, according to the number of crystallizations it has undergone.
But their best refined Salt-petre, even that of the third shooting, is
not yet sufficiently pure for Chymical experiments that require much
accuracy: so that it must be further purified; but still by the same
method.
Public-domain text, read in full here on John Shaqi.
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