Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
From what hath been said concerning the nature of Fire, it is
evidently impossible for us to fix and confine it in any body. Yet the
phenomena attending the combustion of inflammable bodies shew, that
they really contain the matter of Fire as a constituent principle.
By what mechanism then is this fluid, which is so subtle, so active,
so difficult to confine, so capable of penetrating into every other
substance in nature; how comes it, I say, to be so fixed as to make
a component part of the most solid bodies? It is no easy matter to
give a satisfactory answer to this question. But, without pretending
to guess the cause of the phenomenon, let us rest contented with the
certainty of the fact, the knowledge of which will undoubtedly procure
us considerable advantages. Let us therefore examine the properties of
Fire thus fixed, and become a principle of bodies. To this substance,
in order to distinguish it from pure and unfixed Fire, the Chymists
have assigned the peculiar title of the _Phlogiston_, which indeed is
no other than a Greek word for the Inflammable Matter; by which latter
name, as well as by that of the Sulphureous Principle, it is also
sometimes called. It differs from elementary Fire in the following
particulars. 1. When united to a body, it communicates to it neither
heat nor light. 2. It produces no change in its state, whether of
solidity or fluidity; so that a solid body does not become fluid by
the accession of the Phlogiston, and _vice versa_; the solid bodies to
which it is joined being only rendered thereby more apt to be fused by
the force of the culinary fire. 3. We can convey it from the body with
which it is joined into another body, so that it shall enter into the
composition thereof, and remain fixed in it.
On this occasion both these bodies, that which is deprived of the
Phlogiston and that which receives it, undergo very considerable
alterations; and it is this last circumstance, in particular, that
obliges us to distinguish the Phlogiston from pure Fire, and to
consider it as the element of Fire combined with some other substance,
which serves it as a basis for constituting a kind of secondary
principle. For if there were no difference between them, we should be
able to introduce and fix pure Fire itself, wherever we can introduce
and fix the Phlogiston: yet this is what we can by no means do, as will
appear from experiments to be afterwards produced.
Public-domain text, read in full here on John Shaqi.
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