Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
"Of pure urine that has fermented five or six days take a quantity
in proportion to the quantity of phosphorus you intend to make:
it requires about one third part of a hogshead to make a dram of
Phosphorus. Evaporate it in iron pans, till it become clotted, hard,
black, and nearly like chimney-soot; at which time it will be reduced
to about a sixtieth part of its original weight before evaporation.
"When the urine is brought to this condition put it in several portions
into so many iron pots, under which you must keep a pretty brisk fire
so as to make their bottoms red, and stir it incessantly till the
volatile salt and the fetid oil be almost wholly dissipated, till the
matter cease to emit any smoke, and till it smell like peach-blossoms.
Then put out the fire, and pour on the matter, which will now be
reduced to a powder, somewhat more than twice its weight of warm
water. Stir it about in this water, and leave it to soak therein for
twenty-four hours. Pour off the water by inclination; dry the drenched
matter, and pulverize it. The previous calcination carries off from the
matter about a third of its weight, and the lixiviation washes out half
the remainder.
"With what remains thus calcined, washed, and dried, mix half its
weight of gravel, or yellow freestone rasped, having sifted out and
thrown away all the finest particles. River sand is not proper on this
occasion, because it flies in a hot fire. Then add to this mixture a
sixteenth part of its weight of charcoal, made of beech, or of any
other wood except oak, because that also flies. Moisten the whole
with as much water as will bring it to a stiff paste, by working and
kneading it with your hands: now introduce it into your retort, taking
care not to daub its neck. The retort must be of the best earth, and of
such a size, that when your matter is in it, a full third thereof shall
still be empty.
"Place your retort, thus charged, in a reverberating furnace, so
proportioned, that there may be an interval of two inches all round
between the sides of the furnace and the bowl of the retort, even where
it contracts to form the neck, which should stand inclined at an angle
of sixty degrees. Stop all the apertures of the furnace, except the
doors of the fire-place and ash-hole.
"Fit on to the retort a large glass ballon two thirds full of water,
and lute them together, as in distilling the Smoking Spirit of Nitre.
In the hinder part of this ballon, a little above the surface of the
water, a small hole must be bored. This hole is to be stopped with a
small peg of birch-wood, which must slip in and out very easily, and
have a small knob to prevent its falling into the ballon. This peg
is to be pulled out from time to time, that by applying the hand to
the hole it may be known whether the air, rarefied by the head of the
retort, issues out with too much or too little force.
Public-domain text, read in full here on John Shaqi.
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