Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
First, Urine abounds with Sea-salt, and contains also a great deal of
Phlogiston; now these are the ingredients of which they conjecture
Phosphorus to be composed.
Secondly, Phosphorus has many of the properties of Sulphur; such
as being soluble in oils; melting with a gentle heat; being very
combustible; burning without any soot; giving a vivid and blueish
flame; and lastly, leaving an acid liquor when burnt: sensible proofs
that it differs from Sulphur in nothing but the nature of its Acid.
Thirdly, this Acid of Phosphorus, being mixed with a solution of silver
in Spirit of Nitre, precipitates the silver, and this precipitate is
a true _Luna cornea_, which appears to be more volatile even than the
common sort; as M. Hellot tells us, who made the experiment. This
fact proves incontestably that the Acid of Phosphorus is of the same
nature with that of Sea-salt: for all Chymists know that the property
of precipitating silver in a _Luna cornea_ belongs to the Marine Acid
only.
Fourthly, M. Stahl observes, that, if Sea-salt be cast on live coals,
they instantly burn with great activity; then they emit a very
vivid flame, and are much sooner consumed than if none of this salt
had touched them; that Sea-salt in substance, which will bear the
violence of fire a considerable time when fused in a crucible, without
sustaining any sensible diminution, yet evaporates very quickly, and is
reduced to white flowers, by the immediate contact of burning coals;
and, lastly, that the flame which rises on this occasion is of a blue
colour inclining to violet, especially if it be not thrown directly
on the coals themselves, but kept in fusion amidst burning coals, in
a crucible so placed that the vapour of the Salt may join with the
enflamed Phlogiston as it rises from the coals.
These experiments of M. Stahl's prove, that the Phlogiston acts upon
the acid of Sea-salt, even while it is combined with its alkaline
basis. The flame that appears on this occasion may be considered as an
imperfect Phosphorus: and indeed its colour is exactly like that of
Phosphorus.
All the facts above related evince, that the Acid of Phosphorus is akin
to that of Sea-salt; or rather that it is the very same. But there are
other facts which prove that this Acid undergoes some change at least,
some peculiar preparation, before it enters into the composition of a
true Phosphorus, and that, when extricated therefrom by burning, it is
not a pure Acid of Sea-salt, but is still adulterated with a mixture of
some other substance, which makes it considerably different from that
Acid. For these observations we are obliged to M. Marggraff, of the
Academy of Sciences at Berlin, a celebrated Chymist. I shall presently
give an account of his principal experiments as succinctly as possible.
Public-domain text, read in full here on John Shaqi.
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