Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
"If the retort crack while the Phosphorus is distilling, there is an
unsuccessful end of your operation. It is easy to perceive this by the
stink of garlic which you will smell about the furnace; and moreover,
the flame that issues through the apertures of the reverberatory will
be of a beautiful violet colour. The Acid of Sea-salt always gives this
colour to the flame of such matters as are burnt along with it. But
if the retort break before the Phosphorus hath made its appearance,
its contents may be saved by throwing a number of cold bricks into the
fire-place, and upon them a little water to quench the fire at once."
All these useful observations we owe also to M. Hellot.
The Phosphorus here described was first discovered by a citizen
of Hamburgh, named Brandt, who worked upon urine in search of the
Philosopher's stone. Afterwards two other skilful Chymists, who knew
nothing more of the process, than that Phosphorus was obtained from
urine, or, in general, from the human body, likewise endeavoured
to discover it; and each of them separately did actually make the
discovery. These two Chymists were Kunckel and Boyle.
The former perfected the discovery, and found out a method of making it
in considerable quantities at a time; which occasioned it to be called
_Kunckel's Phosphorus_. The other, who was an English gentleman, had
not time to bring his discovery to perfection, and contented himself
with lodging a voucher of his having discovered it in the hands of the
Secretary of the Royal Society of London, who gave him a certificate
thereof.
"Though Brandt," says M. Hellot, "who had before this sold his secret
to a Chymist named Krafft, sold it afterwards to several other persons,
and even at a very low rate; and though Mr. Boyle published the process
for making it; yet it is extremely probable that both of them kept in
their own hands the master-key; I mean, _the particular management
necessary to make the operation succeed_: for, till Kunckel found it
out, no other Chymist ever made any considerable quantity thereof,
except Mr. Godfrey Hankwitz, an English Chymist, to whom Mr. Boyle
revealed the whole mystery.
"Nevertheless," continues he, "we are very far from alledging that
all those who have described this operation meaned to impose upon the
world: but we conceive that most of them having observed luminous
vapours in the ballon, and some sparks about the juncture of the
vessels, were contented with those appearances. And thus it came to
pass, that, after Kunckel and Boyle died, Mr. Godfrey Hankwitz was the
only Chymist that could supply Europe therewith; on which account it is
likewise very well known by the name of _English Phosphorus_."
Almost all the Chymists consider Phosphorus as a substance consisting
of the Acid of Sea-salt combined with the Phlogiston, in the same
manner as Sulphur consists of the Vitriolic Acid combined with the
Phlogiston. This opinion is founded on the following principles.
Public-domain text, read in full here on John Shaqi.
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