Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This Acid effervesces with fixed and volatile Alkalis, and therewith
forms Neutral Salts; but very different from Sea-salt, and from Sal
Ammoniac. That which has a fixed Alkali for its basis does not crackle
when thrown on burning coals; but swells and vitrifies like Borax. That
which has a volatile Alkali for its basis shoots into long pointed
crystals; and, being urged by fire in a retort, lets go its volatile
alkali, a vitrified matter remaining behind. This Salt is like that
above-mentioned, as obtained from urine and yielding Phosphorus.
It appears from the experiments adduced, that the Acid of Phosphorus
tends always to vitrification; which proves that it is not pure, and
gave M. Marggraff cause to think that it is altered by the admixture of
a very subtile vitrifiable earth.
M. Marggraff also obtained Phosphorus from several vegetable substances
which we use every day for food. This gives him occasion to conjecture,
that the Salt requisite to the formation of Phosphorus exists in
vegetables, and passes from thence into the animals that feed upon them.
Lastly, he concludes his dissertation by informing us of a very
important truth, _viz._ That the Acid obtained from Phosphorus, by
burning it, will serve to form Phosphorus anew; for which purpose it
need only be combined with some charred coal, such as lamp-black, and
distilled.
From what hath been said on this subject it is plain, that the Chymists
have a great many curious and interesting inquiries to make concerning
Phosphorus, and particularly concerning its Acid.
I shall conclude this article with an account of certain properties of
Phosphorus which I have not yet mentioned.
Phosphorus dissolves by lying exposed to the air. What water cannot
effect, says M. Hellot, or at least requires eight or ten years to
bring about, the moisture of the air accomplishes in ten or twelve
days; whether it be that the Phosphorus takes fire in the air, and
the inflammable part evaporating, almost entirely, leaves the Acid of
the Phosphorus naked, which, like all other Acids, when exceedingly
concentrated, is very greedy of moisture; or else that the moisture
of the air, being water divided into infinitely fine particles, is so
subtile as to find its way through the pores of the Phosphorus, into
which the grosser particles of common water can by no means insinuate
themselves.
Phosphorus heated by the vicinity of fire, or by being any way rubbed,
soon takes fire and burns fiercely. It is soluble in all Oils and in
Ether, giving to those liquors the property of appearing luminous when
the bottle containing the solution is opened. Being boiled in water,
it likewise communicates thereto this luminous quality. M. Morin,
Professor at Chartres, is the author of this observation.
Public-domain text, read in full here on John Shaqi.
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