Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The late Mr. Grosse, a celebrated Chymist of the Academy of Sciences,
observed, that Phosphorus being dissolved in essential oils
crystallizes therein. These crystals take fire in the air, either when
thrown into a dry vessel, or wrapt up in a piece of paper. If they
be dipped in Spirit of Wine, and taken out immediately, they do not
afterwards take fire in the air: they smoke a little, and for a very
short time, but hardly waste at all. Though some of them were left in
a spoon for a fortnight, they did not seem to have lost any thing of
their bulk: but when the spoon was warmed a little they took fire, just
like common Phosphorus that had never been dissolved and crystallized
in an essential Oil.
M. Marggraff, having put a dram of Phosphorus, with an ounce of highly
concentrated Spirit of Nitre, into a glass retort, observed, that,
without the help of fire, the Acid dissolved the Phosphorus; that part
of the Acid came over into the recipient which was luted to the retort;
that, at the same time, the Phosphorus took fire, burnt furiously, and
burst the vessels with explosion. Nothing of this kind happens when any
of the other Acids, though concentrated, are applied to Phosphorus.
PROCESS III.
_To decompose Sea-salt by means of the Vitriolic Acid. Glauber's Salt.
The Purification and Concentration of Spirit of Salt._
Put the Sea-salt from which you mean to extract the Acid into an
unglazed earthen pipkin, and set it amidst live coals. The Salt will
decrepitate, grow dry, and fall into a powder. Put this decrepitated
Salt into a tubulated glass retort, leaving two thirds thereof empty.
Set the retort in a reverberating furnace; apply a receiver like that
used in distilling the Smoking Spirit of Nitre, and lute it on in the
same manner, or rather more exactly if possible. Then through the
hole, in the upper convexity of the retort, pour a quantity of highly
concentrated Oil of Vitriol, equal in weight to about a third part
of your Salt, and immediately shut the hole very close with a glass
stopple, first ground therein with emery so as to fit it exactly.
As soon as the Oil of Vitriol touches the Salt, the retort and receiver
will be filled with abundance of white vapours; and soon after,
without lighting any fire in the furnace, drops of a yellow liquor
will distil from the nose of the retort. Let the distillation proceed
in this manner without fire, as long as you perceive any drops come:
afterwards kindle a very small fire under the retort, and continue
distilling and raising the fire by very slow degrees, and with great
caution, to the end of the distillation; which will be finished before
you have occasion to make the retort red-hot. Unlute the vessels, and
without delay pour the liquor, which is a very smoking Spirit of Salt,
out of the receiver into a crystal bottle, like that directed for the
smoking Spirit of Nitre.
_OBSERVATIONS._
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