Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Lastly, M. Baron, whom we mentioned before on occasion of this Salt,
hath proved, by a great number of experiments, that a Sedative Salt
may be procured from Borax by the help of Vegetable Acids, which was
never done by any body before him; that the Sedative Salt is not
a combination of an Alkaline matter with the Acid made use of in
extracting it, as some of its properties seemed to indicate; but that
it exists previously and completely formed in the Borax; that the Acid
employed to extract it only helps to disengage it from the Alkali with
which it is united; that this Alkali is actually of the same nature as
the basis of Sea-salt, because that after extracting the Sedative Salt,
which by its union therewith forms the Borax, a Neutral Salt is found,
of the same sort with that which would be produced by combining the
basis of Sea-salt with the particular Acid made use of; that is, if
with the Vitriolic Acid, a Glauber's Salt; if with the Nitrous Acid,
a quadrangular Nitre; and if with the Marine Acid, a true Sea-salt;
and, lastly, that the Sedative Salt may be re-united to its Alkali, and
reproduce a Borax.
Nothing therefore now remains, to give us all the insight we can desire
into the nature of Borax, but to know what the Sedative Salt is. M.
Baron hath already given us certain negative notices concerning it,
by shewing what it is not; that is, that the Acid employed in its
extraction doth not enter into its composition. We have great reason to
hope, that he will carry his inquiries still further, and clear up all
our doubts on this subject.
The Sedative Salt may be extracted from Borax, not only by the means
of pure and simple Acids, but also by the same Acids combined with a
metallic basis. Thus Vitriols, for instance, may be employed for this
purpose with good success. It is easy to see, that the Vitriol must
be decomposed on this occasion, and that its Acid cannot unite with
the Alkali in which the Sedative Salt is lodged, without quitting its
metallic basis, which must of course precipitate.
The Sedative Salt actually sublimes, when a liquid containing it is
distilled; but it does not therefore follow, that it is naturally
volatile. It rises only by the aid of the water with which it is mixed.
The proof of this assertion is, that, when all the humidity of the
mixture containing this Salt is dissipated, no more Salt will rise,
be the fire ever so violent; and that by adding more water to moisten
the dried mass containing it, more Salt will every time be obtained,
through many repeated distillations. In the same manner, if some
Sedative Salt be moistened, and exposed to a proper degree of heat, a
small quantity thereof will rise at first by the help of the water; but
as soon as it grows dry it remains exceedingly fixed. This observation
we owe to M. Rouelle.
Public-domain text, read in full here on John Shaqi.
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