Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
A little phlegm will first come over, and then with the last moisture
that the heat expels the Sedative Salt will rise; by which means some
of it will be dissolved in this last phlegm, and pass therewith into
the receiver; but most of it will adhere in the form of saline flowers
to the fore-part of the neck of the retort, just where it is clear of
the groove of the furnace. There they collect into a heap, which the
succeeding flowers push insensibly forward till they slightly stop the
passage. Those which rise after the neck is thus stopped stick to the
after-part of it which is hot, vitrify in some measure, and form a
circle of fused Salt. In this state the flowers of the Sedative Salt
seem to issue out of the circle, as from their basis: they appear
like very thin, light, shining scales, and must be brushed off with a
feather.
At the bottom of the retort will be left a saline mass: dissolve this
in a sufficient quantity of hot water; filter the solution in order
to free it from a brown earth which it deposites; set the liquor to
evaporate, and crystals of Sedative Salt will form in it.
_OBSERVATIONS._
Though Borax is of great use in many chymical operations, especially in
the fusion of metals, as we shall have occasion to see, yet, till of
late years, Chymists were quite ignorant of its nature, as they still
are of its origin; concerning which we know nothing with certainty, but
that it comes rough from the East Indies, and is purified by the Dutch.
M. Homberg was one of the first that attempted to analyse this Salt. He
shewed, that on mixing it with the Vitriolic Acid, and distilling the
mixture, a salt sublimes in little fine needles. This product of Borax
he called by the name of _Sedative Salt_, because he found it had the
property of moderating the great tumult and heat of the blood in fevers.
After M. Homberg, other Chymists also exercised themselves on Borax. M.
Lemery discovered that the Vitriolic is not the only Acid by means of
which the Sedative Salt may be obtained from Borax; but that either of
the other two Mineral Acids, the Nitrous or the Marine, may be used in
its stead.
M. Geoffroy hath greatly facilitated the means of obtaining the
Sedative Salt from Borax; having shewn that it may be extracted by
crystallization as well as by sublimation; and that the Sedative Salt
so obtained is in no respect inferior to that which was procured before
by sublimation only. To him also we are indebted for the discovery,
that in the composition of Borax there is an Alkaline Salt of the same
nature as the basis of Sea-salt. This he found by observing that he got
a Glauber's Salt from a solution of Borax into which he had poured some
Vitriolic Acid with a view to obtain its Sedative Salt.
Public-domain text, read in full here on John Shaqi.
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