Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Sometimes Gold is intimately combined with such mineral matters as
hinder the Mercury from acting upon it. In that case the mixed mass
must be roasted before you proceed to Amalgamation: for if the matters
be volatile, such, for instance, as antimony or arsenic, the fire
will carry them off; so that, after roasting, the Amalgamation will
succeed. But sometimes these matters are fixed, and require fusion; if
so, recourse must be had to some particular methods, which we shall
describe when we come to treat of Silver, as these two perfect metals
are to be treated in the same manner.
Ores containing Gold must be washed before an Amalgam is attempted;
that the metalline parts, being freed from the numerous particles of
earth with which they are encompassed, may the more readily incorporate
with the Mercury. Besides, it is the property of Mercury to take the
form of a dark unmetallic powder, after being long rubbed with other
matters, so that it cannot be easily distinguished from the particles
of earth. And hence, if you still continue to grind the matters
together, after the Amalgamation is completed, and wash them again
and again, the water that comes off will always look turbid, being
impregnated with some particles of the Amalgam. This is easily proved:
for if you let the turbid water settle, and distil the sediment, you
will obtain Quick-silver from it.
The ore is to be steeped in vinegar charged with alum, in order to
cleanse the surface of the Gold, which is often covered with a thin
coat of earth that obstructs the Amalgamation.
Great care must be taken that the Mercury employed in this operation be
very pure. If it be adulterated with any metallic substance, it must be
freed therefrom by the methods which we shall propose in their proper
place.
The way of separating Mercury from Gold is founded on the different
properties of these two metallic substances; the one being exceedingly
fixed, and the other very volatile. The union which Mercury contracts
with the metals is not intimate enough, to give the new compound which
results therefrom all the properties of either of the two united
substances; at least so far as concerns their degrees of fixity
and volatility. Hence it comes, that, in our Amalgam, the Gold
communicates but very little of its fixity to the Mercury, and the
Mercury communicates to the Gold but very little of its volatility. Yet
if the Mercury be distilled off with a much greater degree of heat than
is necessary to elevate it, a pretty considerable quantity of Gold will
most certainly be carried up along with it.
It is also of consequence, on another account, that the fire be duly
governed on this occasion. For if too great a degree of heat be
applied, and the fire afterwards lowered, the water in the receiver,
which covers the nose of the retort, will rise into its body, break it
to pieces, and spoil the operation.
Public-domain text, read in full here on John Shaqi.
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