Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The cause of this phenomenon depends on the property which air
possesses of rarefying with heat and condensing with cold, joined to
its weight. As soon as the retort is acted on by a less degree of heat
than acted on it the instant before, the air contained therein is
condensed, and leaves a _vacuum_, which the external air, by virtue of
its weight, tends to occupy; but, the orifice of the retort being under
water, the external air can no way gain admittance, but by pushing in
before it the water which intercepts its passage. This caution, as we
observed above, must be applied to all distillations, where the vessels
are disposed as they are in this.
Care must also be taken that the nose of the retort be not placed too
deep under water: for as the neck grows very warm during the operation,
because the degree of heat required to raise Mercury is about three
times greater than that which raises water, it may easily be broken by
the contact of the cold water in the receiver.
This method of extracting Gold and Silver from their ores, by
Amalgamation with Mercury, is not to be absolutely depended on as a
sure proof of the quantity of those metals that may be contained in
the earth assayed by this means: for some small part of the Amalgam is
always lost in washing it; and, moreover, the Mercury, when squeezed
through chamoy, always carries with it a small portion of Gold. So that
if you desire to know more exactly, by this method, the quantity of
Gold or Silver contained in any earth, the Amalgam must not be squeezed
through chamoy, but distilled altogether. Much the surest method of
making an accurate assay is that by fusion and scorification, which we
shall describe under the head of Silver.
In some countries, and especially in America, the method of
Amalgamation is used for extracting Gold and Silver in large
quantities, from the matrices which contain them in their metalline
form. Agricola and other metallurgists have described the machines by
means whereof such Amalgamations are managed.
PROCESS II.
_To dissolve Gold in_ Aqua regis, _and by that means to separate it
from Silver_. Aurum Fulminans. Aurum Fulminans _reduced_.
Take Gold that is perfectly pure, or alloyed with Silver only. Reduce
it to little thin plates, by hammering it on an anvil. If it be not
sufficiently tough, neal it till it be red in a moderate, clear fire,
quite free from smoking coals, and then let it cool gradually, which
will restore its ductility.
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