Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If the Gold put to dissolve in _aqua regis_ be pure, the dissolution
is easily and readily effected. But if, on the contrary, it be alloyed
with Silver, the _aqua regis_ finds more difficulty in dissolving it.
Nay, if the Silver exceed the Gold in quantity, the dissolution will
not take place at all, for the reasons adduced in our Theoretical
Elements; of which we shall speak more fully when we come to treat of
the Parting Assay.
In the process we directed the Gold to be dissolved in a tall body.
This precaution is necessary to prevent the loss of some part thereof:
for it is the property of _aqua regis_ to carry off along with it
some of the Gold, especially when there is any Sal Ammoniac in its
composition, if the vessel be heated while the dissolution is going on,
or if the _aqua regis_ be very strong. Yet it is proper to make use of
_aqua regis_ that is too strong rather than too weak: for if it prove
too strong, and be observed not to act upon the metal for that reason,
it is easy to weaken it, by gradually adding small quantities of pure
water, till you perceive it begin to act with vigour. This is a general
rule regarding all metallic dissolutions in Acids.
When the solution of Gold is evaporated to dryness, if you desire to
reduce into a mass the Gold dust left at the bottom of the cucurbit,
you must put it into a crucible, and cover it with pulverized borax,
mixed with a little nitre and calcined wine-lees; then cover the
crucible close, heat it with a moderate fire, which must be afterwards
increased so as to melt the contents. At the bottom of the crucible you
will find a lump of Gold, over which the salts you added will be as it
were vitrified. These salts are added chiefly to promote the fusion of
the metal.
The Gold may, if you will, be separated from its solvent without
evaporating the solution as above directed. You need only mix with the
solution a fixed or volatile Alkali by little and little, till you see
no more precipitate fall, and then let the liquor stand to settle, at
the bottom of which you will find a sediment: filter the whole, and dry
what is left on the filter.
Both fixed and volatile Alkalis possessing, as hath been frequently
repeated, a greater affinity with Acids than metallic substances have,
they precipitate the Gold, and separate it from the Acids in which it
is dissolved: but it is of great consequence to take notice, that,
if you attempt to melt this precipitated Gold in a crucible, it will
fulminate as soon as it feels the heat, with such a terrible explosion,
that, if the quantity be at all considerable, it may prove fatal to
the operator: even rubbing it a little hard will make it blow up. This
preparation is therefore called _Aurum Fulminans_.
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