Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the plates are thin enough, make them red hot once more, and cut
them into small bits with a pair of sheers. Put these bits into a tall,
narrow-mouthed cucurbit, and pour on them twice their weight of good
_Aqua regis_, made of one part Sal Ammoniac, or Spirit of Salt, and
four parts Spirit of Nitre. Set the cucurbit in a sand-bath moderately
heated, stopping its orifice slightly with a paper coffin, to prevent
any dirt from falling in. The _Aqua regis_ will presently begin to
smoke. Round the little bits of Gold will be formed an infinite number
of small bubbles, which will rise to the surface of the liquor. The
Gold will totally dissolve, if it be pure, and the solution will be of
a beautiful yellow colour: if the Gold be alloyed with a small quantity
of Silver, the latter will remain at the bottom of the vessel in the
form of a white powder. If the Gold be alloyed with much Silver, when
the Gold is dissolved the Silver will retain the form of the little
metalline plates put into the vessel.
When the dissolution is completed, gently pour off the liquor into
another low, wide-mouthed, glass cucurbit, taking care that none of the
Silver, which lies at the bottom in the form of a powder, escape with
the liquor. On this powder of Silver pour as much fresh _Aqua regis_ as
will cover it entirely; and repeat this till you are sure that nothing
more can be taken up by it. Lastly, having decanted the _Aqua regis_
from the Silver, wash the Silver with a little Spirit of Salt weakened
with water, and add this Spirit of Salt to the _Aqua regis_ in which
your Gold is dissolved. Then to the body containing these liquors fit
a head and a receiver, and distil with a gentle heat, till the matter
contained in the cucurbit become dry.
_OBSERVATIONS._
It is certain that _aqua regis_ is the true solvent of Gold, and that
it does not touch Silver: so that if the Gold dissolved in it were
alloyed with Silver, which is often the case, the two metals would by
this means be pretty accurately separated from each other. But if you
desire to obtain from this solution a Gold absolutely pure, you must
free it, before you dissolve it, from every other metallic substance
but Silver; because _aqua regis_ acts upon most of the other metals
and the semi-metals. We shall shew under the head of Silver, as we
promised before, how to purify a mass of Gold and Silver from every
other metallic alloy. Thither also we refer the common parting assay
performed by means of _aqua fortis_: because in that operation the
Silver is dissolved, and not the Gold.
Public-domain text, read in full here on John Shaqi.
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