Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Sixthly, It happens sometimes that when a third substance is presented
to a body consisting of two substances, no decomposition follows;
but the two compounding substances, without quitting each other,
unite with the substance presented to them, and form a combination of
three principles: and this comes to pass when that third substance
has an equal, or nearly equal, Affinity with each of the compounding
substances. The same thing may also happen even when the third
substance hath no Affinity but with one of the compounding substances
only. To produce such an effect, it is sufficient that one of the
two compounding substances have to the third body a Relation equal,
or nearly equal, to that which it has to the other compounding
substance with which it is already combined. Thence it follows, that
two substances, which, when apart from all others, are incapable
of contracting any union, may be rendered capable of incorporating
together in some measure, and becoming parts of the same compound, by
combining with a third substance with which each of them has an equal
Affinity.
Seventhly, A body, which of itself cannot decompose a compound
consisting of two substances, because, as we just now said, they have
a greater affinity with each other than it has with either of them,
becomes nevertheless capable of separating the two by uniting with
one of them, when it is itself combined with another body, having a
degree of Affinity with that one, sufficient to compensate its own want
thereof. In that case there are two Affinities, and thence ensues a
double decomposition and a double combination.
These fundamental truths, from which we shall deduce an explanation
of all the phenomena in Chymistry, will be confirmed and illustrated
by applying them, as we shall do, to the several cases, of which our
design in this treatise obliges us to give a circumstantial account.
CHAP. III.
_Of Saline Substances in general._
If a particle of water be intimately united with a particle of earth,
the result will be a new compound, which, according to our third
proposition of Affinities, will partake of the properties of earth
and of water; and this combination principally forms what is called
a _Saline Substance_. Consequently every Saline Substance must have
an affinity with earth and with water, and be capable of uniting with
both or either of them, whether they be separate or mixed together:
and accordingly this property characterizes all Salts, or Saline
Substances, in general.
Water being volatile and Earth fixed, Salts in general are less
volatile than the former, and less fixed than the latter; that is,
fire, which cannot volatilize and carry off pure earth, is capable of
rarefying and volatilizing a Saline Substance; but then this requires a
greater degree of heat than is necessary for producing the same effects
on pure water.
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