Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Place the test thus loaded under the further end of the muffle in a
cupelling furnace. Light your fire, and increase it by degrees. If you
look through one of the apertures in the door of the furnace you will
perceive the ore, covered with calcined Lead, swim upon the melted
Lead. Presently afterwards it will grow soft, melt, and be thrown
towards the sides of the vessel, the surface of the Lead appearing in
the midst thereof bright and shining like a luminous disc: the Lead
will then begin to boil, and emit fumes. As soon as this happens, the
fire must be a little checked, so that the ebullition of the Lead may
almost entirely cease, for about a quarter of an hour. After this it
must be excited to the degree it was at before, so that the Lead may
begin again to boil and smoke. Its shining surface will gradually
lessen, and be covered with _scoriæ_. Stir the whole with an iron hook,
and draw in towards the middle what you observe towards the sides of
the vessel; to the end that, if any part of the ore should still remain
undissolved by the Lead, it may be mixed therewith.
When you perceive that the matter is in perfect fusion, that the
greatest part of what sticks to the iron hook, when you dip it in the
melted matter, separates from it again, and drops back into the vessel;
and that the extremity of this instrument, when grown cold, appears
varnished over with a thin, smooth, shining crust; you may look on
these as marks that the business is done, and the more uniform and
evenly the colour of the crust is, the more perfect may you judge the
scorification to be.
Matters being brought to this pass, take the test with a pair of tongs
from under the muffle, and pour its whole contents into an iron cone,
first heated and greased with tallow. This whole operation lasts about
three quarters of an hour. When all is cold, the blow of a hammer
will part the Regulus from the scoria; and as it is not possible, how
perfect soever the scorification be, to avoid leaving a little Lead
containing Silver in the scoria, it is proper to pulverize this scoria,
and separate therefrom whatever extends under the hammer, in order to
add it to the Regulus.
_OBSERVATIONS._
Silver, as well as Gold, is often found quite pure, and under its
metalline form, in the bowels of the earth; and in that case it may
be separated from the stones or sand in which it is lodged by simple
washing, or by Amalgamation with Mercury, in the same manner as before
directed for Gold. But it also happens frequently, that Silver is
combined in the ore with other metallic substances and minerals, which
will not admit of this process, but force us to employ other methods of
separating it from them.
Public-domain text, read in full here on John Shaqi.
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