Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
However, unless the evaporation be carried to the utmost, by the means
above pointed out, a small portion of the Regulus of Antimony will
always remain combined with the Gold, which defends it from the action
of the fire. This small portion of Regulus hinders the Gold from being
perfectly pure and ductile. In order therefore to consume and scorify
it, we cast Nitre into the crucible when we perceive it to emit no more
white vapours.
We know that Nitre has the property of reducing all metallic substances
to a calx, Gold and Silver excepted; because it deflagrates with
the phlogiston to which their metalline form is owing: but as this
accension of the Nitre occasions a tumid effervescence, care must be
taken to throw it in but by little and little at a time; for if too
much be projected at once the melted matter will run over.
This operation might be considerably abridged by taking advantage of
the property which Nitre possesses of thus consuming the phlogiston
of metallic substances; as by means thereof we might destroy all the
Regulus of Antimony incorporated with the Gold, without having recourse
to a long and tedious evaporation. But then we should at the same time
lose a much greater quantity of Gold, by reason of the tumult and
ebullition which are inseparable from the detonation of Nitre. On the
whole, therefore, if Nitre be made use of to purify Gold, great care
must be taken to apply but very little of it at a time.
All the Silver that was mixed with the Gold, and indeed a little of
the Gold itself, remains confounded with the sulphureous scoria, which
floats upon the Golden Regulus after the addition of the Antimony: we
shall shew in the Chapter on Silver how these two metals are to be
separated from the Sulphur.
CHAP. II.
_Of_ SILVER.
PROCESS I.
_To separate Silver from its Ore, by means of Scorification with Lead._
Beat to powder in an iron mortar the ore from which you mean to
separate the Silver, having first roasted it well in order to free it
from all the Sulphur and Arsenic that it may contain. Weigh it exactly:
then weigh out by itself eight times as much granulated Lead. Put one
half of this Lead into a test, and spread it equally thereon: upon this
Lead lay your ore, and cover it quite over with the remaining half of
the Lead.
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