Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
We recommended the precaution of slackening the fire a little at the
beginning of the operation, only to prevent the Lead from being too
hastily converted into litharge, lest it should penetrate and corrode
the test before it had wholly dissolved the ore: but if we were
perfectly certain of the vessel's being so good as to be in no danger
of penetration by the Lead, this precaution would be needless.
It is proper to add eight parts of Lead for one of ore; though so
much is not always absolutely necessary, especially when the ore is
very fusible. The success of this operation depends chiefly on the
completeness of the Scorification; and therefore the addition of more
Lead than enough is attended with no inconvenience: for, as it always
promotes the Scorification, it can never do any harm.
If the ore be mixed with such earthy and stony parts as cannot be
separated from it by washing, it is the more difficult of fusion,
even though the stones should be such as are most disposed to vitrify;
because the most fusible earths and stones are always less so than most
metallic substances. In that case it will be necessary, for effecting
the Scorification, to mix thoroughly with the pulverized ore an equal
quantity of Glass of Lead, to add twelve times as much granulated Lead,
and then to proceed as directed for a fusible ore; exposing the mixture
to a degree of fire strong enough, and long enough kept up, to give
the scoria all the properties above required as signs of a perfect
scorification.
Silver ore is sometimes mixed with Pyrites, and the ore of Arsenic, or
Cobalt, which also make it refractory. As the Pyrites contain a large
quantity of Sulphur, which is very volatile as well as Arsenic; in
this case it is proper to begin with freeing the ore from these two
extraneous substances. This is easily done by roasting: only be sure,
when you first expose the ore to the heat, to cover the vessel in which
you roast it, for some minutes, with an inverted vessel of the same
width; because such sorts of ore are very apt to fly when they first
feel the heat.
After this uncover it, and leave it exposed to the fire till no more
sulphureous or arsenical matters rise. Then mix it with the same
quantity of Glass of Lead as we ordered for ores rendered refractory by
the admixture of earths or stones, and proceed in the same manner.
It is the more necessary to roast Silver ore infected with Sulphur and
Arsenic, because, as Sulphur obstructs the fusion of Lead, it cannot
but do hurt, and protract the operation; and Arsenic does mischief, on
the other hand, by scorifying a very great quantity of Lead too hastily.
Public-domain text, read in full here on John Shaqi.
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