Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the Sulphur and Arsenic are dissipated by roasting, the ore must
be treated like that which is rendered refractory by stony and earthy
matters; for as the pyrites contain much iron, there remains, after the
Sulphur is evaporated, a considerable quantity of martial earth, which
is difficult to scorify. The pyrites, as well as the cobalts, contain
moreover an unmetallic earth, which is hard to fuse.
The general rule therefore is, when the ore is rendered refractory
by any cause whatever, to mix it with Glass of Lead, and to add a
larger quantity of granulated Lead. Yet some ores are so refractory
that Lead alone will not do the business, and recourse must be had to
some other flux. That which is fittest for the present purpose is the
_Black Flux_, composed of one part of Nitre and two parts of Tartar
deflagrated together. The Phlogiston contained in this quantity of
Tartar is more than sufficient to alkalizate the Nitre. This Flux,
therefore, is nothing more than Nitre alkalizated by Tartar, mixed with
some of the same Tartar that hath not lost its Phlogiston, and is only
reduced to a sort of coal.
The _White Flux_ is also very fit to promote fusion; but on this
occasion the Black Flux is preferable, because the Phlogiston of the
Black Flux prevents the Lead from being too soon converted to litharge,
and so gives it time to dissolve the metallic matters. The White Flux,
which is the result of equal parts of Tartar and Nitre alkalizated
together, being no more than an Alkali destitute of Phlogiston, or
containing but very little, doth not possess this advantage.
If Silver should be combined in the ore with Iron in its metalline
state, which however does not commonly happen, then, in order to
separate them, the Iron must be deprived of its Phlogiston, and
converted to a _crocus_ before the mixed mass be melted with Lead;
which may be done by dissolving it in the Vitriolic Acid, and then
evaporating the Acid.
We are necessitated to make use of this contrivance, because Iron in
its metalline form cannot be dissolved either by Lead or by the Glass
of Lead; but when it is reduced to a calx, litharge unites with it and
scorifies it.
If you have not at hand the utensils necessary for performing the
operation we have been describing in a test, and under the muffle; or
if you have a mind to work on a greater quantity of ore at a time, you
may make use of a crucible for the purpose, and perform the operation
in a melting furnace.
In this case the ore must be prepared, as above directed, according to
its nature, and mixed with a proper quantity of Lead and Glass of Lead;
the whole put into a good crucible, leaving two thirds thereof empty,
and covered with a mixture of Sea-salt and a little Borax, both very
dry, to the thickness of a full half inch.
Public-domain text, read in full here on John Shaqi.
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