Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Increase the fire by degrees, as more and more litharge is formed and
absorbed. If the Regulus examined by this assay contain no Silver,
you will see it turn wholly into scoria, and at last disappear. When
it contains Silver, and the quantity of Lead is much diminished, you
will perceive little vivid irises, or beautiful rain-bow colours,
shooting swiftly along its surface, and crossing each other in many
different directions. At last, when all the Lead is destroyed, the
thin dark skin, that is continually protruded by the Lead while it is
turning into litharge, and which hitherto covered the Silver, suddenly
disappears; and, if at this moment the fire happen not to be strong
enough to keep the Silver in fusion, the surface of that metal will at
once dart out a dazzling splendour: but, if the fire be strong enough
to keep the Silver in fusion, though freed from all mixture of Lead,
this change of colour, which is called its _fulguration_, will not be
so perceptible, and the Silver will appear like a bead of fire.
These phenomena shew that the operation is finished. But the cupel
must still be left a minute or two under the muffle, and then drawn
slowly out with the iron hook towards the door of the furnace. When the
Silver is so cooled as to be but moderately red, you may take the cupel
from under the muffle with your little tongs, and in the middle of its
cavity you will find an exceeding white bead of Silver, the lower part
whereof will be unequal, and full of little pits.
_OBSERVATIONS._
The Regulus obtained by the former process consists altogether of
the Silver contained in the ore, alloyed with the other metals that
happened to be mixed therewith in its mineral state, and a good deal of
the Lead that was added to precipitate the Silver. The operation of the
cupel may be considered as the sequel of that process, being intended
only to reduce into a scoria whatever is not Gold or Silver. Lead being
of all metals that which vitrifies the most easily, which most promotes
the vitrification of the rest, and the only one which, when vitrified,
penetrates the cupel, and carries along with it the other metals which
it hath vitrified, is consequently the fittest for that purpose. We
shall see in its place, that Bismuth hath the same properties with
Lead, and may be substituted for it in this operation.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account