Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This being done, set the crucible in the midst of a melting furnace,
raise the coals quite to the lip of the crucible; light the fire;
cover the furnace with its dome; but do not urge the fire more than
is necessary to bring the mixture to perfect fusion: leave it thus in
fusion for a good quarter of an hour; stir the whole with a bit of
strong iron wire; then let it cool; break the crucible, and separate
the Regulus from the scoria.
The Salts added on this occasion are fluxes, and their use is to
procure a perfect fusion of the scoria.
If the melted matters be left exposed to the fire, either in a test
or in a crucible, longer than is above prescribed, the portion of
Lead, that hath united and precipitated with the Silver, will at last
vitrify, and at the same time scorify all the alloy with which that
metal may be mixed. But as there are no vessels that can long endure
the action of litharge, without being pierced like a sieve, some of the
Silver may escape through the holes or fissures of the vessel, and so
be lost. It is better, therefore, to complete the purification of your
Silver by the operation of the Cupel, the description of which follows.
PROCESS II.
_The refining of Silver by the Cupel._
Take a cupel capable of containing one third more matter than you
have to put into it: set it under the muffle of a furnace, like that
described in our Theoretical Elements, as peculiarly appropriated to
this sort of operation. Fill the furnace with charcoal; light it; make
the cupel red-hot, and keep it so till all its moisture be evaporated;
that is, for about a good quarter of an hour, if the cupel be made
wholly of the ashes of burnt bones; and for a whole hour, if there be
any washed wood-ash in its composition.
Reduce the Regulus which remained after the preceding operation to
little thin plates, flatting them with a small hammer, and separating
them carefully from all the adherent scoria. Wrap these in a bit of
paper, and with a small pair of tongs put them gently into the cupel.
When the paper is consumed the Regulus will soon melt, and the scoria,
which will be gradually produced by the Lead as it turns to litharge,
will be driven to the sides of the cupel, and immediately absorbed
thereby. At the same time the cupel will assume a yellow, brown, or
blackish colour, according to the quantity and nature of the scoria
imbibed by it.
When you see the matter in the cupel in a violent ebullition, and
emitting much smoke, lower the fire by the methods formerly prescribed.
Keep up such a degree of heat only that the smoke which ascends
from the matter may not rise very high, and that you may be able to
distinguish the colour which the cupel acquires from the scoria.
Public-domain text, read in full here on John Shaqi.
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