Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If the fume emitted by the Lead rise like a spout to the roof of
the muffle; if the surface of the melted metal be extremely convex,
considering the quantity of the mass: if the cupel appear of such a
white heat, that the colour communicated thereto by the imbibed scoria
cannot be distinguished: all these shew that the heat is too great, and
that it ought to be diminished. If, on the contrary, the vapours only
hover, as it were, over the surface of the metal; if the melted mass
be very flat, considering its quantity; if its ebullition appear but
faint; if the _scoriæ_, that appear like little fiery drops of rain,
have but a languid motion; if the scoria gather in heaps, and do not
penetrate the cupel; if the metal be covered with it as with a glassy
coat; and, lastly, if the cupel look dull; these are proofs that the
heat is too weak, and ought to be increased.
The design of this operation being to convert the Lead into litharge,
and to give it sufficient time and opportunity to scorify and carry
off with it whatever is not Gold or Silver; the fire must be kept up
to such a degree that the Lead may easily be turned into litharge, and
yet that litharge not be absorbed too hastily by the cupel, but that
a small quantity thereof may all along remain, like a ring, round the
melted metal.
The fire is to be gradually increased as the operation draws nearer
to its end: for, as the proportion of the Lead to the Silver is
continually lessening, the metallic mass gradually becomes less
fusible; while the Silver defends the Lead mixed with it from the
action of the fire, and prevents its being easily converted into
litharge.
When the operation is finished, the cupel must still be left under
the muffle, till it has imbibed all the litharge, to the end that the
bead of Silver may be easily taken out: for, without this precaution,
it would stick so fast as not to be removed, but by breaking off part
of the cupel along with it. Care must also be taken to let this bead
of Silver cool gradually, and be perfectly fixed, before you draw it
from under the muffle; for if you expose it at once to the cold air,
before it be fixed, it will swell, shoot into sprigs, and even dart out
several little grains to a considerable distance, which will be lost.
If the bead appear to have a yellowish tinge, it is a sign that it
contains a great deal of Gold, which must be separated from it by the
methods to be hereafter shewn.
Public-domain text, read in full here on John Shaqi.
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