Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It is proper to observe, that there is scarce any Lead that does not
contain some Silver; too little perhaps to defray the charges necessary
to separate it, yet considerable enough to lead us into an error, by
mixing with the Silver obtained from an ore, and increasing its weight.
And therefore, when the operations above described are applied to the
assaying of an ore, in order to know how much Silver it yields, it is
previously necessary to examine the Lead to be used, and to ascertain
the quantity of Silver it contains, which must be deducted from the
total weight of the bead of Silver obtained by purifying it in this
manner.
Silver may be separated from its ore, and at the same time refined, by
the single operation of the cupel, without any previous scorification
with Lead. In order to do this, you must pound the ore; roast it, to
dissipate all its volatile parts; mix it with an equal quantity of
litharge, if it be refractory; divide it into five or six parcels,
wrapping each in a bit of paper; weigh out eight parts of granulated
Lead for one of ore, if it be fusible, and from twelve to sixteen,
if it be refractory; put one half of the Lead into a very large
cupel under the muffle; add thereto one of the little parcels of
ore, when the Lead begins to smoke and boil; immediately slacken the
fire a little; continue the same degree of heat till you perceive
that the litharge formed round the metal, and on its surface, begins
to look bright; then raise the fire; add a fresh parcel of ore;
continue proceeding in the same manner till you have put in all the
ore; then add the remaining half of the granulated Lead, and conduct
the succeeding part of the operation in the same manner as that of
cupelling.
In this operation it is necessary that the fire be not too strongly
urged, and that it be diminished every time you add a fresh
parcel of ore; that so the Lead and the litharge may have time
to dissolve, scorify, and carry off into the pores of the cupel,
all the adventitious matters with which your Silver may be mixed.
Notwithstanding this precaution, when the ore is refractory, there
often gathers in the cupel a great quantity of scoria, together also
with some of the ore that could not be dissolved and scorified. It is
with a view to remedy this inconvenience that the second moiety of the
Lead is added towards the end, which completes the dissolution and
scorification of the whole; so that by means thereof no scoria, or very
little, is left in the cupel at the end of the operation.
Public-domain text, read in full here on John Shaqi.
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