Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
_Aqua fortis_ is the true solvent of Silver, and is utterly incapable
of dissolving the least atom of Gold. If therefore a mass consisting of
Gold and Silver be exposed to the action of _aqua fortis_, that Acid
will dissolve the Silver contained in the compound, without touching
the Gold, and the two metals will be separated from each other. This
method of parting them is just the reverse of that described before
under the head of Gold, which is effected by the means of _aqua regis_.
To the success of this separation, by means of _aqua fortis_, several
conditions are essentially necessary. The first is, that the Gold and
Silver be in due proportion to each other; that is, there must be at
least twice as much Silver as Gold in the metalline mass, otherwise the
_aqua fortis_ will not be able to dissolve it, for the reason formerly
given. If therefore the mass contain too little Silver, it must either
be melted down again, and a proper quantity of Silver added; or else,
if the Gold be in a sufficient proportion to the Silver, they may be
parted by means of _aqua regis_.
Secondly, it is necessary that the _aqua fortis_ employed in this
operation be absolutely pure, and free from any taint of the Vitriolic
or Marine Acid: for, if it be adulterated with the Vitriolic Acid,
the Silver will precipitate as fast as it dissolves, and so the
precipitated Silver will again mix with the Gold. If the _aqua fortis_
contain any of the Marine Acid, the Silver will be precipitated in
that case also; and this inconvenience will be attended with another,
namely, that the menstruum, being partly an _aqua regis_, will dissolve
some of the Gold. You must therefore be very sure that your _aqua
fortis_ is pure, before you set about the operation. In order to
discover its quality, you must try it by dissolving, in a small portion
thereof, as much Silver as it will take up: if the _aqua fortis_ grow
opaque and milky as it dissolves the Silver, it is a sign it contains
some foreign Acid, from which it must be purified.
In order to effect this, let the portion of _aqua fortis_ used for the
above trial stand to settle: the white milky part will gradually fall
to the bottom of the vessel. When it is all fallen, gently decant the
clear liquor, and pour a few drops of this decanted solution of Silver
into the _aqua fortis_ which you want to purify. It will instantly
become milky. Let the white particles precipitate as before, and then
add a few more drops of your solution of Silver. If the _aqua fortis_
still become milky, let it precipitate again, and repeat this till you
find that a drop of your solution of Silver, let fall into this _aqua
fortis_, does not make it in the least turbid. Then filter it through
brown paper, and you will have an _aqua fortis_ perfectly fit for the
Parting Assay.
Public-domain text, read in full here on John Shaqi.
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