Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The white particles that appear and settle to the bottom, on dissolving
silver in an _aqua fortis_ adulterated with a mixture of some foreign
Acid, are no other than that very Silver, which is no sooner dissolved
by the Nitrous Acid than it deserts that solvent to unite with the
Vitriolic or Marine Acid, wherewith it has a greater affinity, and
falls to the bottom with them. And this happens as long as there
remains in the _aqua fortis_ a single atom of either of those two Acids.
When therefore your _aqua fortis_ hath dissolved as much Silver as it
is capable of taking up, and when all the white particles formed during
the dissolution are settled to the bottom, you may be assured that
the portion which remains clear and limpid is a solution of Silver in
an exceeding pure _aqua fortis_. But if the solution of Silver thus
depurated be mixed with an _aqua fortis_ adulterated with the Vitriolic
or Marine Acid, a like precipitation will immediately ensue, for the
reasons above given, till the very last particle of the heterogeneous
Acid contained in the _aqua fortis_ be precipitated.
_Aqua fortis_ purified by this method contains no extraneous substance
whatever, except a small portion of Silver; so that it is very fit for
the parting process. But if it be intended for other chymical purposes,
it must be rectified in a glass retort with a moderate heat, in order
to separate it from the small portion of Silver it contains, which will
remain at the bottom of the retort.
The third condition necessary to the success of this operation is, that
your _aqua fortis_ be neither too aqueous, nor too highly concentrated.
If too weak, it will not act upon the Silver: and the consequence will
be the same if it be too strong. Both these inconveniencies are easily
remedied: for in the former case part of the superfluous phlegm may be
drawn off by distillation; or a sufficient quantity of much stronger
_aqua fortis_ may be mixed with that which is too weak: and, in the
latter case, very pure rain water, or a weaker _aqua fortis_, may be
mixed with that which is too strong.
You may satisfy yourself whether or no your _aqua fortis_ hath the
requisite degree of strength, by dissolving therein a thin plate
consisting of one part Gold and two or three parts Silver; which plate
must be rolled up in form of a paper coffin. If, when all the Silver
contained in the plate is dissolved, the Gold remains in the form
of the coffin, it is a sign that your solvent has a due degree of
strength. If, on the contrary, the Gold be reduced to a powder, it is a
proof that your _aqua fortis_ is too strong, and ought to be weakened.
The Gold remaining after the dissolution of the Silver must be melted
in a crucible with Nitre and Borax, as hath already been said under the
process for parting Gold and Silver by means of _aqua regis_. As to the
Silver which remains dissolved in the _aqua fortis_, there are several
ways to recover it.
Public-domain text, read in full here on John Shaqi.
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