Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Fresh Acid is poured on the precipitated calx of Silver, in order to
complete the solution of the small portion of Copper that may have
escaped the action of the first solvent. It is indifferent whether
the Spirit of Salt or the Spirit of Nitre be employed for this
purpose, because they both dissolve Copper alike, and because Silver
precipitated by Spirit of Salt is not soluble in either.
After this it is necessary to wash the precipitate well with pure
water, in order to free it entirely from the particles of _aqua fortis_
adhering to the Silver; because they may possibly contain something
of Copper, which would mix with the Silver in melting, and taint its
purity.
If this precipitate of Silver be exposed to the fire, unmixed with any
other substance, it melts as soon as it begins to be red; and, if the
fire be increased, part thereof will be dissipated in vapours, and the
rest will make its way through the crucible. But being poured out as
soon as melted, it coagulates into a cake of a purplish red colour,
semi-transparent, ponderous, and in some degree pliable, especially
if it be very thin. It bears some resemblance to horn, which hath
occasioned it to be called _Luna Cornea_.
As _Luna Cornea_ is not soluble in water, recourse must be had to
fusion, in order to reduce it, by separating from the Silver those
acids which give it the above-mentioned properties. Fixed Alkalis and
fatty matters are very fit to produce that separation.
We directed that the inside of the crucible, in which the reduction is
to be made, should be carefully smeared with soap, and that the _Luna
Cornea_ should be quite covered with a Fixed Alkali and fat, to the end
that when the heat is strong enough to dissipate it in vapours, or to
attenuate it so as to render it capable of penetrating the crucible, it
may be forced to pass through matters qualified to absorb its Acid, and
reduce it.
_Luna Cornea_ may also be reduced by being melted with such metalline
substances as have a greater affinity than Silver with the Acids
wherewith it is impregnated. Of this kind are Tin, Lead, Regulus of
Antimony: but the _Luna Cornea_ rushes so impetuously into conjunction
with those metalline substances, that a vast many vapours arise, and
carry off with them part of the Silver: if therefore you chuse to
effect the reduction by the interposition of such metalline substances,
you must employ a retort instead of a crucible.
But this method is attended with another inconvenience; which is, that
some part of those metalline substances may unite with the Silver, and
adulterate it: for which reason it is best to keep to the method first
proposed.
PROCESS VII.
_To dissolve Silver, and separate it from Gold, by Cementation._
Public-domain text, read in full here on John Shaqi.
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