Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Mix thoroughly together fine brick-dust four parts, Vitriol calcined to
redness one part, and Sea-salt or Nitre one part. Moisten this powder
with a little water. With this cement cover the bottom of a crucible
half an inch thick; on this first bed lay a thin plate of the mass of
Gold and Silver you intend to cement, and which you must previously
take care to beat into such thin plates. Cover this plate with a second
layer of cement, of the same thickness as the former; on this second
bed lay another plate of your metal; cover it in like manner with
cement; and so proceed till the crucible be filled to within half an
inch of its brim. Fill up the remaining space with cement, and close
the crucible with a cover, luted with a paste made of Windsor-loam and
water: set your crucible thus charged in a furnace, whose fire-place
is deep enough to let it be entirely surrounded with coals, quite up to
its mouth. Light some coals in the furnace, taking care not to make the
fire very brisk at first; increase it by degrees, but only so far as to
make the crucible moderately red; keep up the fire in this degree for
eighteen or twenty hours: then let the fire go out; open the crucible
when it is cold, and separate the cement from your plates of Gold.
Boil the Gold repeatedly in fair water, till the water come off quite
insipid.
_OBSERVATIONS._
It cannot but seem strange, that, after having so often declared the
Acid of Sea-salt to be incapable of dissolving Silver, we should
direct either Nitre or Sea-salt indifferently to be employed in
composing a cement, which is to produce an Acid capable of eating
out all the Silver mixed with Gold. It is easy to conceive how the
Nitrous Acid extricated from its basis by means of the Vitriolic Acid
may produce this effect: but if Sea-salt instead of Nitre be made an
ingredient in the cement, its Acid, though set at liberty in the same
manner by the Vitriolic Acid, must at first sight appear unable to
answer the end.
In order to remove this difficulty, we must here observe, that there
are two very essential differences between the Marine Acid collected
in a liquor, as it is when distilled in the usual manner, and the same
Acid separated from its basis in a crucible, as it is in cementation.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account