Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The crucible is covered, and its cover luted on, to prevent the acid
vapours from being too soon dissipated, and to force them to circulate
the longer in the crucible. However, it is necessary that those vapours
should find a vent at last, otherwise they would burst the vessel:
and for this reason we directed the crucible to be luted only with
Windsor-loam, which does not grow very hard by the action of fire, and
so is capable of yielding and giving passage to the vapours, when a
certain quantity of them is collected in the crucible, and they begin
to struggle for an escape on every side.
When the operation is finished, the Silver dissolved by the Acid of
the cement is partly distributed through the cement, and partly in the
Gold itself, which is impregnated therewith. For this reason the Gold
must be washed several times in boiling water, till the water become
absolutely insipid: for, if the Gold be melted without this precaution,
it will mix again with the Silver: the cement also may be washed in the
same manner to recover the Silver it contains.
Though this cementation be, properly speaking, a purification of
Gold, yet we have placed it among the processes on Silver, because it
is the Silver that is dissolved on this occasion, and because this
is a particular way of dissolving that metal. Moreover, most of the
processes hitherto delivered, either on Gold or Silver, are equally
applicable to both these metals.
If the Gold do not appear quite pure after the cementation, the process
must be repeated.
There are several ways to know the fineness of Gold, the quantity of
Silver with which it is alloyed, and the proportion in which these two
metals are mixed in a mass purified by the cupel.
One of the simplest is the trial by the Touch-stone; which indeed is
hardly any more than judging by the eye only, from the colour of the
compound metal, what proportion of Gold and Silver it contains.
The Touch-stone is a sort of black marble, whose surface ought to be
half polished. If the metalline mass which you want to try be rubbed
on this stone, it leaves thereon a thin coat of metal, the colour of
which may be easily observed. Such as are accustomed to see and handle
Gold and Silver can at once judge very nearly from this sample in what
proportion the two metals are combined: but, for greater accuracy,
those who are in the way of having frequent occasion for this trial
are provided with a sufficient number of small bars or needles, of
which one is pure Gold, another pure Silver, and all the rest consist
of these two metals mixed together in different proportions, varied
by carats, or even by fractions of carats, if greater exactness be
required.
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