Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The first of these two differences is, that the Acid being reduced
into vapours when it acts on the Silver in cementation, its activity
is thereby greatly increased: the second is, that in the crucible it
sustains a vastly greater degree of heat than it can ever bear when
it is in the form of a liquor. For, after it is once distilled and
separated from its basis, it cannot sustain any extraordinary degree
of heat without being volatilized and entirely dissipated: whereas,
while it continues united with its basis, it is much more fixed, and
cannot be separated but by a very intense heat. Consequently, if it
meet with any body to dissolve, at the very instant of its separation
from its basis, while it is actuated by a much fiercer heat than can
ever be applied to it on any other occasion, it must operate upon that
body with so much the more efficacy: and thus it comes to pass, that in
cementation it has the power of dissolving Silver, which it would be
incapable of touching if it were not so circumstanced.
But herein Gold differs from Silver: for, whatever force the Nitrous
or the Marine Acid may exert, when extricated from their bases in the
cementing crucible, this metal obstinately refuses to yield to either
of those Acids separately, and can never be dissolved by them, unless
both be united together.
Our cementation, therefore, is actually a parting process in the dry
way. The Silver is dissolved, and the Gold remains unaltered. Nay, as
the action of the Acids is much stronger when they are applied this
way, than when they are used for dissolution in the moist way, the
Nitrous Acid, which in the common parting process will not dissolve
Silver unless its weight be double that of the Gold, is able in
cementation to dissolve a very small quantity of Silver diffused
through a large quantity of Gold.
It sometimes happens, that after the operation the cement proves
extremely hard, so that it is very troublesome to separate it entirely
from the Gold. In this case it must be softened by moistening it with
hot water. This hardness which the cement acquires is occasioned by
the fusion of the Salts, which is the effect of too strong a heat. It
was in order to prevent this, and that a due degree of heat might be
applied, without the danger of melting the salts, that we directed
the cement to be mixed with a considerable quantity of earthy matter
incapable of fusion, such as brick-dust. A greater inconvenience will
ensue, if the fire be made so strong as to melt the Gold: for then it
will partly commix again with the other metalline substances dissolved
by the cement, and consequently will not be purified.
Public-domain text, read in full here on John Shaqi.
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