Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The colour of Steel is not so white as that of Iron, but darker, and
the grains, facets, or fibres, which appear on breaking it, are finer
than those observed in Iron.
If the bars of Iron thus cemented in order to convert them into Steel
be too thick, or not kept long enough in cementation, they will not be
turned into Steel throughout their whole thickness: their surfaces only
will be Steel to a certain depth, and the center will be mere Iron;
because the phlogiston will not have thoroughly penetrated them. On
breaking a bar of this sort, the difference in colour and grain between
the Steel and the Iron is very visible.
It is easy to deprive Steel of the super-abundant quantity of phlogiston
which constitutes it Steel, and thereby reduce it to Iron. For this
purpose it need only be kept red-hot some time, observing that no
matter approach it all the while that is capable of refunding to it
the phlogiston which the fire carries off. The same end is still
sooner obtained by cementing it with meagre hungry matters, capable
of absorbing the phlogiston; such as bones calcined to whiteness, and
cretaceous earths.
Steel may also be made by fusion; or Pig-iron may be converted into
Steel. For this purpose the same method must be employed as was
above directed for reducing Pig-iron into malleable Iron; with this
difference, that, as Steel requires more phlogiston than is necessary
to Iron, all the means must be made use of that are capable of
introducing into the Iron a great deal of phlogiston; such as melting
but a small quantity of Iron at a time, and keeping it constantly
encompassed with abundance of charcoal; reiterating the fusions; taking
care that the blast of the bellows directed along the surface of the
metal do not remove the coals that cover it, _&c._ And here it must
be observed, that there are some sorts of Pig-iron which it is very
difficult to convert into Steel by this method, and that there are
others which succeed very readily, and with scarce any trouble at all.
The ores which yield the last-mentioned sort of Pig-iron are called
_Steel Ores_. Steel made by this means must be tempered in the same
manner as that made by cementation[8].
[8] M. Réaumur hath obliged the public with a treatise on the means
of converting Iron into Steel, in which he hath exhausted the subject.
Such as desire the amplest and most useful instructions on that part
of metallurgy, would do well to consult his Work.
PROCESS IV.
_The Calcination of Iron. Sundry Saffrons of Mars._
Take filings of Iron, in what quantity you please; put them into a
broad unglazed earthen vessel; set it under the muffle of a cupelling
furnace; make it red-hot; stir the filings frequently; and keep up the
same degree of fire till the Iron be wholly turned into a red powder.
_OBSERVATIONS._
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